Synthesis of Thiophene Derivatives as π-conjugated linker Photosensitized Dyes

碩士 === 國立臺北科技大學 === 有機高分子研究所 === 98 === In this thesis, several triphenylamine dyes, containing high hole mobility of thienothiophene , bithiophene and n-hexyl-substituted thienothiophene as π-conjugated linker, were synthesized . The organic dyes with the structure of donor-conjugated chain-acce...

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Bibliographic Details
Main Authors: Chih-Hong Huang, 黃志弘
Other Authors: 張淑美
Format: Others
Language:zh-TW
Published: 2010
Online Access:http://ndltd.ncl.edu.tw/handle/233yrn
Description
Summary:碩士 === 國立臺北科技大學 === 有機高分子研究所 === 98 === In this thesis, several triphenylamine dyes, containing high hole mobility of thienothiophene , bithiophene and n-hexyl-substituted thienothiophene as π-conjugated linker, were synthesized . The organic dyes with the structure of donor-conjugated chain-acceptor have been synthesized for dye sensitized solar cell (DSSC). The effects of both the length of the π-conjugated unit and of the alkyl chain up on the photophysical, electrochemical and photovoltaic properties of the dyes were studied. All of these compounds were characterized by UV/VIS spectrophotometer, fluorescence spectrophotometer and cyclic voltammetry. The photoconversion of these compounds were inspected using the AM 1.5 simulated solar light system.