Group 16 (Se or Te)−Containing Manganese or Iron Carbonyl Clusters: Synthesis, Reactivities, Physical Properties, and Theoretical Calculations

博士 === 國立臺灣師範大學 === 化學系 === 98 === 1. Te/Fe/CO System   When [TeFe3(CO)9]2− was treated with [Cu(MeCN)4][BF4] in various ratios, a Te─Fe─Cu chain polymer [{TeFe3(CO)9Cu}−] and a neutral cluster TeFe3(CO)9Cu2(MeCN)2 were formed, respectively. TeFe3(CO)9Cu2(MeCN)2 underwent skeleton expansion to f...

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Bibliographic Details
Main Author: 何佳樺
Other Authors: 謝明惠
Format: Others
Language:en_US
Published: 2009
Online Access:http://ndltd.ncl.edu.tw/handle/85416807054072067192