A Study on Synthesis and Chemical Sensor Application of Iridium(Ⅲ) Complexes
碩士 === 國立成功大學 === 化學系碩博士班 === 97 === A series of iridium complexes [Ir(��2-ppy)2(py′)Cl] was synthesized (Hppy = 2-phenylpyridine; py′ = 4-pyCOOH (5a), 3-pyCOOH (5b), 2-pyCOOH (5c), 4-pyCHO (5d), 4-pyCOOEt (5e), 3,4-py(COOEt)2 (5f), 3,5-py(COOEt)2 (5g), 4-pyCOO－PPN＋(5h), py (5i), 4-pyNH2 (5j), 4-pyO...
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2009
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| Online Access: | http://ndltd.ncl.edu.tw/handle/17668905509820070435 |
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ndltd-TW-097NCKU50650152016-05-04T04:25:26Z http://ndltd.ncl.edu.tw/handle/17668905509820070435 A Study on Synthesis and Chemical Sensor Application of Iridium(Ⅲ) Complexes 銥(Ⅲ)價錯合物的合成與化學感測應用之研究 TZU-CHIH SU 蘇子智 碩士 國立成功大學 化學系碩博士班 97 A series of iridium complexes [Ir(��2-ppy)2(py′)Cl] was synthesized (Hppy = 2-phenylpyridine; py′ = 4-pyCOOH (5a), 3-pyCOOH (5b), 2-pyCOOH (5c), 4-pyCHO (5d), 4-pyCOOEt (5e), 3,4-py(COOEt)2 (5f), 3,5-py(COOEt)2 (5g), 4-pyCOO－PPN＋(5h), py (5i), 4-pyNH2 (5j), 4-pyOH (5k), 4-pyCMe3 (5l)). All complexes were characterized by EA, IR,NMR, UV-Vis and fluorescence spectroscopy. Seven single-crystal structures of complexes 5a, 5b, 5c, 5e, 5f, 5g and 5i were also determined.The chemical-sensing experiments indicate that complex 5a shows a better selectivity toward pyridine bases than other complexes. Kom-Bei Shiu 許拱北 2009 學位論文 ; thesis 89 zh-TW |
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碩士 === 國立成功大學 === 化學系碩博士班 === 97 === A series of iridium complexes [Ir(��2-ppy)2(py′)Cl] was synthesized (Hppy = 2-phenylpyridine; py′ = 4-pyCOOH (5a), 3-pyCOOH (5b), 2-pyCOOH (5c), 4-pyCHO (5d), 4-pyCOOEt (5e), 3,4-py(COOEt)2 (5f), 3,5-py(COOEt)2 (5g), 4-pyCOO－PPN＋(5h), py (5i), 4-pyNH2 (5j), 4-pyOH (5k), 4-pyCMe3 (5l)). All complexes were characterized by EA, IR,NMR, UV-Vis and fluorescence spectroscopy. Seven single-crystal structures of complexes 5a, 5b, 5c, 5e, 5f, 5g and 5i were also determined.The chemical-sensing experiments indicate that complex 5a shows a better selectivity toward pyridine bases than other complexes.
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| author2 |
Kom-Bei Shiu |
| author_facet |
Kom-Bei Shiu TZU-CHIH SU 蘇子智 |
| author |
TZU-CHIH SU 蘇子智 |
| spellingShingle |
TZU-CHIH SU 蘇子智 A Study on Synthesis and Chemical Sensor Application of Iridium(Ⅲ) Complexes |
| author_sort |
TZU-CHIH SU |
| title |
A Study on Synthesis and Chemical Sensor Application of Iridium(Ⅲ) Complexes |
| title_short |
A Study on Synthesis and Chemical Sensor Application of Iridium(Ⅲ) Complexes |
| title_full |
A Study on Synthesis and Chemical Sensor Application of Iridium(Ⅲ) Complexes |
| title_fullStr |
A Study on Synthesis and Chemical Sensor Application of Iridium(Ⅲ) Complexes |
| title_full_unstemmed |
A Study on Synthesis and Chemical Sensor Application of Iridium(Ⅲ) Complexes |
| title_sort |
study on synthesis and chemical sensor application of iridium(ⅲ) complexes |
| publishDate |
2009 |
| url |
http://ndltd.ncl.edu.tw/handle/17668905509820070435 |
| work_keys_str_mv |
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