The study of copper-catalyzed cross-coupling reactions of C-O bond using salicylic acid as a ligand

碩士 === 國立中興大學 === 化學系所 === 97 === We used salicylic acid as ligand with different copper catalysts for C-O bond cross-coupling reaction, and find that CuI is more efficient than CuBr as a catalyst. This efficient catalyst system is: 20 mol% of CuI or CuBr2 as copper source, 20 mol% of salicylic acid...

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Main Authors: Shih-Hsien Hu, 胡世憲
Other Authors: Yao-Jung Chen
Format: Others
Language:zh-TW
Published: 2009
Online Access:http://ndltd.ncl.edu.tw/handle/62850794265541983512
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spelling ndltd-TW-097NCHU50650482016-04-29T04:20:02Z http://ndltd.ncl.edu.tw/handle/62850794265541983512 The study of copper-catalyzed cross-coupling reactions of C-O bond using salicylic acid as a ligand 利用水楊酸配位基對銅催化碳-氧鍵交互偶合反應之研究 Shih-Hsien Hu 胡世憲 碩士 國立中興大學 化學系所 97 We used salicylic acid as ligand with different copper catalysts for C-O bond cross-coupling reaction, and find that CuI is more efficient than CuBr as a catalyst. This efficient catalyst system is: 20 mol% of CuI or CuBr2 as copper source, 20 mol% of salicylic acid as ligand, Cs2CO3 as base, and dioxane as solvent for arylation of phenols, or alkyl alcohols as solvents for arylation of alkyl alcohols. Yao-Jung Chen 陳耀鐘 2009 學位論文 ; thesis 78 zh-TW
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description 碩士 === 國立中興大學 === 化學系所 === 97 === We used salicylic acid as ligand with different copper catalysts for C-O bond cross-coupling reaction, and find that CuI is more efficient than CuBr as a catalyst. This efficient catalyst system is: 20 mol% of CuI or CuBr2 as copper source, 20 mol% of salicylic acid as ligand, Cs2CO3 as base, and dioxane as solvent for arylation of phenols, or alkyl alcohols as solvents for arylation of alkyl alcohols.
author2 Yao-Jung Chen
author_facet Yao-Jung Chen
Shih-Hsien Hu
胡世憲
author Shih-Hsien Hu
胡世憲
spellingShingle Shih-Hsien Hu
胡世憲
The study of copper-catalyzed cross-coupling reactions of C-O bond using salicylic acid as a ligand
author_sort Shih-Hsien Hu
title The study of copper-catalyzed cross-coupling reactions of C-O bond using salicylic acid as a ligand
title_short The study of copper-catalyzed cross-coupling reactions of C-O bond using salicylic acid as a ligand
title_full The study of copper-catalyzed cross-coupling reactions of C-O bond using salicylic acid as a ligand
title_fullStr The study of copper-catalyzed cross-coupling reactions of C-O bond using salicylic acid as a ligand
title_full_unstemmed The study of copper-catalyzed cross-coupling reactions of C-O bond using salicylic acid as a ligand
title_sort study of copper-catalyzed cross-coupling reactions of c-o bond using salicylic acid as a ligand
publishDate 2009
url http://ndltd.ncl.edu.tw/handle/62850794265541983512
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