Application of Tautomerism of Ferrocenyl Secondary Phosphine Oxides in Suzuki Cross Coupling Reactions

碩士 === 國立中興大學 === 化學系所 === 97 === Ferrocenyl secondary phosphine oxides (η5-C5H5)(η5-C5H4-P(=O)(tBu)(H))Fe (5a)、 (η5-C5H5)(η5-C5H4-P(=O)(Cy)(H))Fe (5b)、 (η5-C5H5)(η5-C5H4-P(=O)(Ph)(H))Fe (5c)were prepared. The molecular structures of 5a and 6、7 were determined by single-crystal X-ray diffraction met...

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Main Authors:	Lin-Ying Jung, 鐘琳媖
Other Authors:	HONG, Fung-E
Format:	Others
Language:	zh-TW
Published:	2009
Online Access:	http://ndltd.ncl.edu.tw/handle/89375609714037236316

id	ndltd-TW-097NCHU5065042
record_format	oai_dc
spelling	ndltd-TW-097NCHU50650422016-04-29T04:19:43Z http://ndltd.ncl.edu.tw/handle/89375609714037236316 Application of Tautomerism of Ferrocenyl Secondary Phosphine Oxides in Suzuki Cross Coupling Reactions 含二茂鐵具互變異構之二級氧化磷基應用於Suzuki偶合反應之研究 Lin-Ying Jung 鐘琳媖碩士國立中興大學化學系所 97 Ferrocenyl secondary phosphine oxides (η5-C5H5)(η5-C5H4-P(=O)(tBu)(H))Fe (5a)、 (η5-C5H5)(η5-C5H4-P(=O)(Cy)(H))Fe (5b)、 (η5-C5H5)(η5-C5H4-P(=O)(Ph)(H))Fe (5c)were prepared. The molecular structures of 5a and 6、7 were determined by single-crystal X-ray diffraction methods. Palladium-catalyzed Suzuki reactions employing 5a as ligands gave satisfactory results. Judging from these results, a tautomeric equilibrium between 5a and its isomeric form (( HONG, Fung-E 洪豐裕 2009 學位論文 ; thesis 146 zh-TW
collection	NDLTD
language	zh-TW
format	Others
sources	NDLTD
description	碩士 === 國立中興大學 === 化學系所 === 97 === Ferrocenyl secondary phosphine oxides (η5-C5H5)(η5-C5H4-P(=O)(tBu)(H))Fe (5a)、 (η5-C5H5)(η5-C5H4-P(=O)(Cy)(H))Fe (5b)、 (η5-C5H5)(η5-C5H4-P(=O)(Ph)(H))Fe (5c)were prepared. The molecular structures of 5a and 6、7 were determined by single-crystal X-ray diffraction methods. Palladium-catalyzed Suzuki reactions employing 5a as ligands gave satisfactory results. Judging from these results, a tautomeric equilibrium between 5a and its isomeric form ((
author2	HONG, Fung-E
author_facet	HONG, Fung-E Lin-Ying Jung 鐘琳媖
author	Lin-Ying Jung 鐘琳媖
spellingShingle	Lin-Ying Jung 鐘琳媖 Application of Tautomerism of Ferrocenyl Secondary Phosphine Oxides in Suzuki Cross Coupling Reactions
author_sort	Lin-Ying Jung
title	Application of Tautomerism of Ferrocenyl Secondary Phosphine Oxides in Suzuki Cross Coupling Reactions
title_short	Application of Tautomerism of Ferrocenyl Secondary Phosphine Oxides in Suzuki Cross Coupling Reactions
title_full	Application of Tautomerism of Ferrocenyl Secondary Phosphine Oxides in Suzuki Cross Coupling Reactions
title_fullStr	Application of Tautomerism of Ferrocenyl Secondary Phosphine Oxides in Suzuki Cross Coupling Reactions
title_full_unstemmed	Application of Tautomerism of Ferrocenyl Secondary Phosphine Oxides in Suzuki Cross Coupling Reactions
title_sort	application of tautomerism of ferrocenyl secondary phosphine oxides in suzuki cross coupling reactions
publishDate	2009
url	http://ndltd.ncl.edu.tw/handle/89375609714037236316
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Application of Tautomerism of Ferrocenyl Secondary Phosphine Oxides in Suzuki Cross Coupling Reactions

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