Novel Synthesis and Mesophase studies of A Series of 2-(6-alkoxynaphthalene)-5-phenylpyridines

碩士 === 輔仁大學 === 化學系 === 97 === This study describes the facile synthesis of a homologous of pyridine-containing liquid crystalline 2-(6-alkoxynaphthalen-2-yl)-5-phenylpyridines (nONpPyP, n=3-7). The subject liquid crystals were prepard in a short two-step reaction. First, (6-alkoxynaphthalen-2-yl)ma...

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Main Authors: LIN CHIH HSUN, 林志勳
Other Authors: CHIA WIN LONG
Format: Others
Language:zh-TW
Published: 2009
Online Access:http://ndltd.ncl.edu.tw/handle/99495974077629352404
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spelling ndltd-TW-097FJU000650052015-10-13T13:08:48Z http://ndltd.ncl.edu.tw/handle/99495974077629352404 Novel Synthesis and Mesophase studies of A Series of 2-(6-alkoxynaphthalene)-5-phenylpyridines 一系列2-(6-烷氧萘環)-5-苯基吡啶化合物之新合成方法及液晶性質之研究 LIN CHIH HSUN 林志勳 碩士 輔仁大學 化學系 97 This study describes the facile synthesis of a homologous of pyridine-containing liquid crystalline 2-(6-alkoxynaphthalen-2-yl)-5-phenylpyridines (nONpPyP, n=3-7). The subject liquid crystals were prepard in a short two-step reaction. First, (6-alkoxynaphthalen-2-yl)magnesium bromides were added to N-phenyloxycarbonyl-3-phenyl-pyridinium chloride, affording a dihydropyridine, which was then oxidized by o-chloranil. The resulting products, 2-(6-alkoxynaphthalen-2-yl)-5-phenylpyridines, were obtained in fair yield (35%~40%). Thermotropic behaviors of these liquid crystals were investigated using differential scanning calorimetry(dsc) and polarized optical microscopy(pom). CHIA WIN LONG 賈文隆 2009 學位論文 ; thesis 119 zh-TW
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language zh-TW
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description 碩士 === 輔仁大學 === 化學系 === 97 === This study describes the facile synthesis of a homologous of pyridine-containing liquid crystalline 2-(6-alkoxynaphthalen-2-yl)-5-phenylpyridines (nONpPyP, n=3-7). The subject liquid crystals were prepard in a short two-step reaction. First, (6-alkoxynaphthalen-2-yl)magnesium bromides were added to N-phenyloxycarbonyl-3-phenyl-pyridinium chloride, affording a dihydropyridine, which was then oxidized by o-chloranil. The resulting products, 2-(6-alkoxynaphthalen-2-yl)-5-phenylpyridines, were obtained in fair yield (35%~40%). Thermotropic behaviors of these liquid crystals were investigated using differential scanning calorimetry(dsc) and polarized optical microscopy(pom).
author2 CHIA WIN LONG
author_facet CHIA WIN LONG
LIN CHIH HSUN
林志勳
author LIN CHIH HSUN
林志勳
spellingShingle LIN CHIH HSUN
林志勳
Novel Synthesis and Mesophase studies of A Series of 2-(6-alkoxynaphthalene)-5-phenylpyridines
author_sort LIN CHIH HSUN
title Novel Synthesis and Mesophase studies of A Series of 2-(6-alkoxynaphthalene)-5-phenylpyridines
title_short Novel Synthesis and Mesophase studies of A Series of 2-(6-alkoxynaphthalene)-5-phenylpyridines
title_full Novel Synthesis and Mesophase studies of A Series of 2-(6-alkoxynaphthalene)-5-phenylpyridines
title_fullStr Novel Synthesis and Mesophase studies of A Series of 2-(6-alkoxynaphthalene)-5-phenylpyridines
title_full_unstemmed Novel Synthesis and Mesophase studies of A Series of 2-(6-alkoxynaphthalene)-5-phenylpyridines
title_sort novel synthesis and mesophase studies of a series of 2-(6-alkoxynaphthalene)-5-phenylpyridines
publishDate 2009
url http://ndltd.ncl.edu.tw/handle/99495974077629352404
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