Enantioselective Addition of Diethylzinc to Benzaldehyde Using Pinene Derived Amino Alcohols as Catalysts

碩士 === 朝陽科技大學 === 應用化學系碩士班 === 97 === In thesis a study, we used natural (+)-α-pinene as a starting material to synthesize a series of novel N-substituted aminoalcohols. These aminoalcohols have been used as catalysts for the enantioselective addition reaction of diethylzinc to benzaldehyde. We have...

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Main Authors: Min-Chia Tseng, 曾敏佳
Other Authors: Chi-Tung Hsu
Format: Others
Language:zh-TW
Published: 2009
Online Access:http://ndltd.ncl.edu.tw/handle/55252656164148166451
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spelling ndltd-TW-097CYUT55000102015-10-13T12:05:42Z http://ndltd.ncl.edu.tw/handle/55252656164148166451 Enantioselective Addition of Diethylzinc to Benzaldehyde Using Pinene Derived Amino Alcohols as Catalysts N-取代蒎烯胺醇類的合成及其在二乙基鋅加成反應中的應用 Min-Chia Tseng 曾敏佳 碩士 朝陽科技大學 應用化學系碩士班 97 In thesis a study, we used natural (+)-α-pinene as a starting material to synthesize a series of novel N-substituted aminoalcohols. These aminoalcohols have been used as catalysts for the enantioselective addition reaction of diethylzinc to benzaldehyde. We have found that different aminoalcohols may catalyze the addition reaction to obtain various ratio of enantiomers, albeit that the enantioselectivity is not as high as what we expected. Chi-Tung Hsu 徐基東 2009 學位論文 ; thesis 150 zh-TW
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description 碩士 === 朝陽科技大學 === 應用化學系碩士班 === 97 === In thesis a study, we used natural (+)-α-pinene as a starting material to synthesize a series of novel N-substituted aminoalcohols. These aminoalcohols have been used as catalysts for the enantioselective addition reaction of diethylzinc to benzaldehyde. We have found that different aminoalcohols may catalyze the addition reaction to obtain various ratio of enantiomers, albeit that the enantioselectivity is not as high as what we expected.
author2 Chi-Tung Hsu
author_facet Chi-Tung Hsu
Min-Chia Tseng
曾敏佳
author Min-Chia Tseng
曾敏佳
spellingShingle Min-Chia Tseng
曾敏佳
Enantioselective Addition of Diethylzinc to Benzaldehyde Using Pinene Derived Amino Alcohols as Catalysts
author_sort Min-Chia Tseng
title Enantioselective Addition of Diethylzinc to Benzaldehyde Using Pinene Derived Amino Alcohols as Catalysts
title_short Enantioselective Addition of Diethylzinc to Benzaldehyde Using Pinene Derived Amino Alcohols as Catalysts
title_full Enantioselective Addition of Diethylzinc to Benzaldehyde Using Pinene Derived Amino Alcohols as Catalysts
title_fullStr Enantioselective Addition of Diethylzinc to Benzaldehyde Using Pinene Derived Amino Alcohols as Catalysts
title_full_unstemmed Enantioselective Addition of Diethylzinc to Benzaldehyde Using Pinene Derived Amino Alcohols as Catalysts
title_sort enantioselective addition of diethylzinc to benzaldehyde using pinene derived amino alcohols as catalysts
publishDate 2009
url http://ndltd.ncl.edu.tw/handle/55252656164148166451
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