Study on [ 3+2 ] cycloaddition of L-proline and (E)-ethyl 4-oxobut-2-enoate

碩士 === 國立中正大學 === 化學所 === 97 === The first part of this study involved 1, 3-dipolar cycloaddition of L-proline and (E)-ethyl 4-oxobut-2-enoate. The structure was determined by NMR, and the mechanism was proposed. The second part of this study involved the preparation of some α, β –unsaturated al...

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Bibliographic Details
Main Authors: Shu-wei Shiu, 許書瑋
Other Authors: Bor-Cheng Hong
Format: Others
Language:zh-TW
Published: 2009
Online Access:http://ndltd.ncl.edu.tw/handle/15267388181607106857
Description
Summary:碩士 === 國立中正大學 === 化學所 === 97 === The first part of this study involved 1, 3-dipolar cycloaddition of L-proline and (E)-ethyl 4-oxobut-2-enoate. The structure was determined by NMR, and the mechanism was proposed. The second part of this study involved the preparation of some α, β –unsaturated aldehydes, and the study in the proline-catalysted self-condensation.