| Summary: | 碩士 === 國立中央大學 === 化學研究所 === 96 === Our experiment is aimed to investigate, including for the nitrogen absorption and fluorescence in the 45-60 nm region, atomic emission in particular wavelengths from 46.4 to 61.7 nm, and nitrogen resonance fluorescence of c4’(0) and b(1) states.
We employed the light source at the Seya, U9 and high flux beamlines of National Synchrotron Radiation Research Center in Hsin-Chu, and measure two channels of fluorescence and one of nitrogen absorption in uv-visible (180-650 nm) and VUV (115-320nm ) by using PMTs. In 12-25 eV, the VUV fluorescence, observed clearly in higher resolution than one of P. Erman, is produced by the Codling Rydberg states, converging to C 2Σu+ nsσg state with n= 4, 5 of N2+ C-X emission and D2Πgi nlλ state with n=3 of N2+ D-A emission. All these spectra are compared with the absorption spectrum in 45-50 nm and 50-55 nm regions that we focus.
In the history of nitrogen spectra, we observed directly resonance fluorescence of c4’(0) and b(1) state and atomic emission produced by the photofragment with the combination of the multichannel plate(MCP) and position sensitive detector(PSD) at the synchrotron radiation facility. Speaking of atom emission, it is also shown on MCP in some particular wavelengths from 98 nm to 150 nm when excited nitrogen atoms (2P, 4P, 4D) are produced. Finally, we conclude the cause and find the result of the spectra in this thesis.
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