Synthesis, Characterization and Molecular Structure Studies by NMR Spectroscopy and X-Ray Single-Crystal Determination On Metalloporphyrins : M(Por)(L)n, M = Tl、Cd, Por = (N-NCO(o-Cl)C6H4-tpp)

碩士 === 國立中興大學 === 化學系所 === 96 === We use (N-NHCO(o-Cl)C6H4-Htpp) to react with Tl(OAc)3 and Cd(OAc)2 and form (Tl(N-NCO(o-Cl)C6H4-tpp)(OAc)•H2O) and Cd(N-NCO(o-Cl)C6H4-tpp)(OAc)•CH2Cl2). Because (Zn(N-NCO(o-Cl)C6H4-tpp)(MeOH)) and (Zn(N-NHCO(o-Cl)C6H4-tpp)(Cl)) have been synthesized, we use 1H-1H CO...

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Main Authors:	Kwan-Tin Chen, 陳冠廷
Other Authors:	Jyh-Horung Chen
Format:	Others
Language:	zh-TW
Published:	2008
Online Access:	http://ndltd.ncl.edu.tw/handle/66051650339135519568

id	ndltd-TW-096NCHU5065025
record_format	oai_dc
spelling	ndltd-TW-096NCHU50650252016-05-11T04:16:24Z http://ndltd.ncl.edu.tw/handle/66051650339135519568 Synthesis, Characterization and Molecular Structure Studies by NMR Spectroscopy and X-Ray Single-Crystal Determination On Metalloporphyrins : M(Por)(L)n, M = Tl、Cd, Por = (N-NCO(o-Cl)C6H4-tpp) 利用核磁共振光譜儀及X-光單晶繞射儀探討金屬大環錯化合物，M(Por)(L)n之分子結構，其中M=鉈、鎘，Por=(N-NCO(o-Cl)C6H4-tpp) Kwan-Tin Chen 陳冠廷碩士國立中興大學化學系所 96 We use (N-NHCO(o-Cl)C6H4-Htpp) to react with Tl(OAc)3 and Cd(OAc)2 and form (Tl(N-NCO(o-Cl)C6H4-tpp)(OAc)•H2O) and Cd(N-NCO(o-Cl)C6H4-tpp)(OAc)•CH2Cl2). Because (Zn(N-NCO(o-Cl)C6H4-tpp)(MeOH)) and (Zn(N-NHCO(o-Cl)C6H4-tpp)(Cl)) have been synthesized, we use 1H-1H COSY、HSQC、HMBC(heteronuclear multiple bond coherence) and DEPT to analyse the NMR data and X-ray Single-Crystal Diffractometer to determine the structure and compare the differences. Jyh-Horung Chen 陳志鴻 2008 學位論文 ; thesis 144 zh-TW
collection	NDLTD
language	zh-TW
format	Others
sources	NDLTD
description	碩士 === 國立中興大學 === 化學系所 === 96 === We use (N-NHCO(o-Cl)C6H4-Htpp) to react with Tl(OAc)3 and Cd(OAc)2 and form (Tl(N-NCO(o-Cl)C6H4-tpp)(OAc)•H2O) and Cd(N-NCO(o-Cl)C6H4-tpp)(OAc)•CH2Cl2). Because (Zn(N-NCO(o-Cl)C6H4-tpp)(MeOH)) and (Zn(N-NHCO(o-Cl)C6H4-tpp)(Cl)) have been synthesized, we use 1H-1H COSY、HSQC、HMBC(heteronuclear multiple bond coherence) and DEPT to analyse the NMR data and X-ray Single-Crystal Diffractometer to determine the structure and compare the differences.
author2	Jyh-Horung Chen
author_facet	Jyh-Horung Chen Kwan-Tin Chen 陳冠廷
author	Kwan-Tin Chen 陳冠廷
spellingShingle	Kwan-Tin Chen 陳冠廷 Synthesis, Characterization and Molecular Structure Studies by NMR Spectroscopy and X-Ray Single-Crystal Determination On Metalloporphyrins : M(Por)(L)n, M = Tl、Cd, Por = (N-NCO(o-Cl)C6H4-tpp)
author_sort	Kwan-Tin Chen
title	Synthesis, Characterization and Molecular Structure Studies by NMR Spectroscopy and X-Ray Single-Crystal Determination On Metalloporphyrins : M(Por)(L)n, M = Tl、Cd, Por = (N-NCO(o-Cl)C6H4-tpp)
title_short	Synthesis, Characterization and Molecular Structure Studies by NMR Spectroscopy and X-Ray Single-Crystal Determination On Metalloporphyrins : M(Por)(L)n, M = Tl、Cd, Por = (N-NCO(o-Cl)C6H4-tpp)
title_full	Synthesis, Characterization and Molecular Structure Studies by NMR Spectroscopy and X-Ray Single-Crystal Determination On Metalloporphyrins : M(Por)(L)n, M = Tl、Cd, Por = (N-NCO(o-Cl)C6H4-tpp)
title_fullStr	Synthesis, Characterization and Molecular Structure Studies by NMR Spectroscopy and X-Ray Single-Crystal Determination On Metalloporphyrins : M(Por)(L)n, M = Tl、Cd, Por = (N-NCO(o-Cl)C6H4-tpp)
title_full_unstemmed	Synthesis, Characterization and Molecular Structure Studies by NMR Spectroscopy and X-Ray Single-Crystal Determination On Metalloporphyrins : M(Por)(L)n, M = Tl、Cd, Por = (N-NCO(o-Cl)C6H4-tpp)
title_sort	synthesis, characterization and molecular structure studies by nmr spectroscopy and x-ray single-crystal determination on metalloporphyrins : m(por)(l)n, m = tl、cd, por = (n-nco(o-cl)c6h4-tpp)
publishDate	2008
url	http://ndltd.ncl.edu.tw/handle/66051650339135519568
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Synthesis, Characterization and Molecular Structure Studies by NMR Spectroscopy and X-Ray Single-Crystal Determination On Metalloporphyrins : M(Por)(L)n, M = Tl、Cd, Por = (N-NCO(o-Cl)C6H4-tpp)

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