Modification of Molecular Wire Comprising Redox-Active Biferrocenyl Spacer : Study of Electrochemistry and Photophysical Properties

碩士 === 國立中山大學 === 化學系研究所 === 95 === In attempting to modulate the electronic properties of molecular-wire Ru(II) complexes, we now describe an interesting example of X-tpy-Ru2+-tpy-(fc)2-tpy-Ru2+-tpy -X ( fc = ferrocenyl ; tpy = terpyridyl ; X=Cl, OMe, OH ) complexes comprising electronic donor or w...

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Main Authors: Hung-Yu Lin, 林虹妤
Other Authors: Teng-Yuan Dong
Format: Others
Language:zh-TW
Published: 2007
Online Access:http://ndltd.ncl.edu.tw/handle/53n7r7
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spelling ndltd-TW-095NSYS50650032019-05-15T20:22:41Z http://ndltd.ncl.edu.tw/handle/53n7r7 Modification of Molecular Wire Comprising Redox-Active Biferrocenyl Spacer : Study of Electrochemistry and Photophysical Properties 修飾具氧化還原活性雙二茂鐵為架橋基之分子導線:電化學與光物理性質之探討 Hung-Yu Lin 林虹妤 碩士 國立中山大學 化學系研究所 95 In attempting to modulate the electronic properties of molecular-wire Ru(II) complexes, we now describe an interesting example of X-tpy-Ru2+-tpy-(fc)2-tpy-Ru2+-tpy -X ( fc = ferrocenyl ; tpy = terpyridyl ; X=Cl, OMe, OH ) complexes comprising electronic donor or withdrawing group attached directly to the 4’-position of the terminal tpy moiety. The ground-state HOMO and LUMO energies were probed by electrochemical measurements and the excited-state photophysical properties were probed by absorption spectroscopy. Teng-Yuan Dong 董騰元 2007 學位論文 ; thesis 143 zh-TW
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language zh-TW
format Others
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description 碩士 === 國立中山大學 === 化學系研究所 === 95 === In attempting to modulate the electronic properties of molecular-wire Ru(II) complexes, we now describe an interesting example of X-tpy-Ru2+-tpy-(fc)2-tpy-Ru2+-tpy -X ( fc = ferrocenyl ; tpy = terpyridyl ; X=Cl, OMe, OH ) complexes comprising electronic donor or withdrawing group attached directly to the 4’-position of the terminal tpy moiety. The ground-state HOMO and LUMO energies were probed by electrochemical measurements and the excited-state photophysical properties were probed by absorption spectroscopy.
author2 Teng-Yuan Dong
author_facet Teng-Yuan Dong
Hung-Yu Lin
林虹妤
author Hung-Yu Lin
林虹妤
spellingShingle Hung-Yu Lin
林虹妤
Modification of Molecular Wire Comprising Redox-Active Biferrocenyl Spacer : Study of Electrochemistry and Photophysical Properties
author_sort Hung-Yu Lin
title Modification of Molecular Wire Comprising Redox-Active Biferrocenyl Spacer : Study of Electrochemistry and Photophysical Properties
title_short Modification of Molecular Wire Comprising Redox-Active Biferrocenyl Spacer : Study of Electrochemistry and Photophysical Properties
title_full Modification of Molecular Wire Comprising Redox-Active Biferrocenyl Spacer : Study of Electrochemistry and Photophysical Properties
title_fullStr Modification of Molecular Wire Comprising Redox-Active Biferrocenyl Spacer : Study of Electrochemistry and Photophysical Properties
title_full_unstemmed Modification of Molecular Wire Comprising Redox-Active Biferrocenyl Spacer : Study of Electrochemistry and Photophysical Properties
title_sort modification of molecular wire comprising redox-active biferrocenyl spacer : study of electrochemistry and photophysical properties
publishDate 2007
url http://ndltd.ncl.edu.tw/handle/53n7r7
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