| Summary: | 碩士 === 國立高雄師範大學 === 化學系 === 95 === Abstract
The main object of this research is to develop the highly transparent polymeric film with the anti-static property. In order to enhance the miscibility between the inorganic and the organic phases,the silanol coupling agent is made from the slane VTMS（vinyltrimathoxysilane） and the colloid silica. Then the silanol coupling agent and nano-particles of ZnSb2O6 as the conductive filler are successfully bonded and the nano-particles of ZnSb2O6 will become more organic-like. The colloid silane-SiO2-ZnSb2O6 precursor solution is subsequently mixed with a homogeneous lsopropylalcohol solution of SR-399 acrylic monomers (Dipentaerythritol pentaacrylate) and the active free radical agent709 (photo initiator). Under nitrogen purging, this reaction solution prepolymerize at 60℃. Then, the solution is spin-coated with the spin coator at room temperature. At last, the coated thin film is cured and crosslinked by the UV curing reactor to form the highly transparent thin film with good optoelectronic properties from hybrid organic-inorganic nano-composite.
The conductive filler content , the reaction procedure as well as the curing conditions will be the control parameters to this study. The morphology structure of nano-composite film will be investigated by SEM. The properties including the thermal properties, the electrical conductivity and the light transparency will be measured and discussed. Finally, the potential of these new synthetic films applied in the optical field will be evluated.
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