Synthesis, Characterization and Cross-coupling Applications of Palladacycles Bearing C,N,S-donor Benzamidine Ligands

碩士 === 中興大學 === 化學系所 === 95 === Treatment of three novel tridentate C,N,S-donor ligand precursors1-3 with palladium(II) salts afforded orthometallated palladium(II) complexes 4-9. Crystal structures are reported for complexs 5-8 and 5’. The application of these novel palladacyclic complexes as catal...

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Bibliographic Details
Main Authors:	Wei-Chi Wang, 王維麒
Other Authors:	陳繼添
Format:	Others
Language:	zh-TW
Published:	2007
Online Access:	http://ndltd.ncl.edu.tw/handle/02780603893178672449

id	ndltd-TW-095NCHU5065054
record_format	oai_dc
spelling	ndltd-TW-095NCHU50650542015-10-13T14:13:11Z http://ndltd.ncl.edu.tw/handle/02780603893178672449 Synthesis, Characterization and Cross-coupling Applications of Palladacycles Bearing C,N,S-donor Benzamidine Ligands 具碳-氮-硫配位形式benzamidine鈀環錯合物之合成、鑑定及其在偶合催化反應之應用 Wei-Chi Wang 王維麒碩士中興大學化學系所 95 Treatment of three novel tridentate C,N,S-donor ligand precursors1-3 with palladium(II) salts afforded orthometallated palladium(II) complexes 4-9. Crystal structures are reported for complexs 5-8 and 5’. The application of these novel palladacyclic complexes as catalyses for the Suzuki and Heck reactions with aryl halide substrates was examined, affording coupled products in good to excellent yields.Of particular note, complex 6 showed high TON value up to 106 with 4-Bromoacetophenone in Suzuki reaction. 陳繼添 2007 學位論文 ; thesis 144 zh-TW
collection	NDLTD
language	zh-TW
format	Others
sources	NDLTD
description	碩士 === 中興大學 === 化學系所 === 95 === Treatment of three novel tridentate C,N,S-donor ligand precursors1-3 with palladium(II) salts afforded orthometallated palladium(II) complexes 4-9. Crystal structures are reported for complexs 5-8 and 5’. The application of these novel palladacyclic complexes as catalyses for the Suzuki and Heck reactions with aryl halide substrates was examined, affording coupled products in good to excellent yields.Of particular note, complex 6 showed high TON value up to 106 with 4-Bromoacetophenone in Suzuki reaction.
author2	陳繼添
author_facet	陳繼添 Wei-Chi Wang 王維麒
author	Wei-Chi Wang 王維麒
spellingShingle	Wei-Chi Wang 王維麒 Synthesis, Characterization and Cross-coupling Applications of Palladacycles Bearing C,N,S-donor Benzamidine Ligands
author_sort	Wei-Chi Wang
title	Synthesis, Characterization and Cross-coupling Applications of Palladacycles Bearing C,N,S-donor Benzamidine Ligands
title_short	Synthesis, Characterization and Cross-coupling Applications of Palladacycles Bearing C,N,S-donor Benzamidine Ligands
title_full	Synthesis, Characterization and Cross-coupling Applications of Palladacycles Bearing C,N,S-donor Benzamidine Ligands
title_fullStr	Synthesis, Characterization and Cross-coupling Applications of Palladacycles Bearing C,N,S-donor Benzamidine Ligands
title_full_unstemmed	Synthesis, Characterization and Cross-coupling Applications of Palladacycles Bearing C,N,S-donor Benzamidine Ligands
title_sort	synthesis, characterization and cross-coupling applications of palladacycles bearing c,n,s-donor benzamidine ligands
publishDate	2007
url	http://ndltd.ncl.edu.tw/handle/02780603893178672449
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Synthesis, Characterization and Cross-coupling Applications of Palladacycles Bearing C,N,S-donor Benzamidine Ligands

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