| Summary: | 碩士 === 國立高雄應用科技大學 === 化學工程系碩士班 === 95 === Abstract
The paper focused on the UV cure behavior of bismaleimide and the UV imidization of the polyamid acid. The materials utilized here were classified two major categories.
The first category (Part I) is the additional type of polyimide. Two monomer, BMI (1,1’-(methylened- 4,1-phenylene)-bismaleimide) and BMIP (2,2-bis(4-(4 maleimido phenoxy) phenyl propane), were chosen for the UV cure behavior studies in this category.
The second category (Part II) is the condensation type of polyimide. A polyamide acid (PAA) was preliminarily synthesized by the ODA(4,4-Oxydianoiline) and PMDA (Pyromellitic dianhydride), subsequently imidized by UV light to form the polyimide.
One kinetic equation containing reaction order(n), photointensity(Q), energy barrier for photoinitiation (EQ), photoinitiator concentration (I) , reaction temperature (T) and apparent activation energy(Ea) was successfully derived as follows.
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