The Syntheses of Benzo[c]thiophene, Isobenzofuran and Benzo[c]pyrrole Derivatives with Cyano and Ester Groups
碩士 === 國立中正大學 === 化學所 === 95 === The major goal of this dissertation is to synthesize isobenzofuran, isoindole and benzo[c]thiophene derivatives with cyano and ester groups substituted at 5,6 positions. Using heterocyclic aromatic 3,4-dialdehyde compounds as starting materials, we successfully empl...
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| Format: | Others |
| Language: | zh-TW |
| Online Access: | http://ndltd.ncl.edu.tw/handle/64539053924601170419 |
| Summary: | 碩士 === 國立中正大學 === 化學所 === 95 === The major goal of this dissertation is to synthesize isobenzofuran, isoindole and benzo[c]thiophene derivatives with cyano and ester groups substituted at 5,6 positions. Using heterocyclic aromatic 3,4-dialdehyde compounds as starting materials, we successfully employed an elongation cycloaromatization strategy developed in our group to achieve these structures. In addition, ortho-dibenzoyl acenes are used as starting materials to synthesize naphtho[c]thiophene and naphtho[c]pyrrole derivatives. The fundamental photophysical and electrochemical properties of these new compounds are measured. Their potential applications in optoelecrical devices are also discussed.
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