The Synthesis of New Molecular Clips and Their Possible Applications

• Main Authors: Li-Chieh Wen, 溫力潔
• Other Authors: 邱勝賢
• Format: Others
• Language: zh-TW
• Published: 2006
• Online Access: http://ndltd.ncl.edu.tw/handle/29417004162698897138

碩士 === 國立臺灣大學 === 化學研究所 === 94 === Abstract : We have reported the synthesis of a molecular clip with TTF (tetrathiafuvalene) as the sidewalls and its binding behavior towards a macrocycle in which an electron-deficient pyridinium unit was present. This macrocycle/molecular-clip complex functions as a quadruply controllable molecular switch for the addition and removal of heat, metal ions, protons, electrons. To extend the application of this molecular clip system, we plan to synthesize new molecular clips that present suitable functionalities as their “feet”. We believe that these functional groups can be used to anchor the molecular clips onto the surfaces of gold nanoparticles. Therefore, the behavior of supramolecular complexes can be carried out at the surfaces of solid states.