1. Approach to the kempane skeleton via intramolecular Diels-Alder cycloaddition of fulvene 2. Application of organocatalysts in Baylis-Hillman reaction and related cycloaddition

1. Approach to the kempane skeleton via intramolecular Diels-Alder cycloaddition of fulvene 2. Application of organocatalysts in Baylis-Hillman reaction and related cycloaddition

博士 === 國立中正大學 === 化學所 === 94 === Part 1: Approach to the kempane skeleton via intramolecular Diels-Alder cycloaddition of fulvene The Kempane skeletons can be prepared rapidly via intramolecular Diels-Alder cycloadditions (IMDA) of fulvenes. The chemistry upon both intramolecular Diels-Alder cyclo...

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Main Authors: Shang-Hong Chen, 陳尚鴻
Other Authors: none
Format: Others
Language:zh-TW
Published: 2006
Online Access:http://ndltd.ncl.edu.tw/handle/51860899827903256040
id ndltd-TW-094CCU05065019
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spelling ndltd-TW-094CCU050650192015-10-13T10:45:17Z http://ndltd.ncl.edu.tw/handle/51860899827903256040 1. Approach to the kempane skeleton via intramolecular Diels-Alder cycloaddition of fulvene 2. Application of organocatalysts in Baylis-Hillman reaction and related cycloaddition 1.利用富烯化合物進行分子內Diels-Alder環化加成反應合成Kempane骨架之研究2.有機催化劑應用在Baylis-Hillman反應及[3+3]和[4+2]環化加成反應之研究 Shang-Hong Chen 陳尚鴻 博士 國立中正大學 化學所 94 Part 1: Approach to the kempane skeleton via intramolecular Diels-Alder cycloaddition of fulvene The Kempane skeletons can be prepared rapidly via intramolecular Diels-Alder cycloadditions (IMDA) of fulvenes. The chemistry upon both intramolecular Diels-Alder cycloadditions and Prins reaction. Part 2: Application of organocatalysts in Baylis-Hillman reaction and related cycloaddition A highly enantioselective proline catalyzed intramolecular Baylis–Hillman reaction of hept-2-enedial is reported. Addition of imidazole to the mixture results in an unusual inversion of enantioselectivity. The organocatalyzed [3 + 3] and [4+2] cycloaddition of ?β-unsaturated aldehydes affored aromatic aldehydes. none 洪伯誠 2006 學位論文 ; thesis 546 zh-TW
collection NDLTD
language zh-TW
format Others
sources NDLTD
description 博士 === 國立中正大學 === 化學所 === 94 === Part 1: Approach to the kempane skeleton via intramolecular Diels-Alder cycloaddition of fulvene The Kempane skeletons can be prepared rapidly via intramolecular Diels-Alder cycloadditions (IMDA) of fulvenes. The chemistry upon both intramolecular Diels-Alder cycloadditions and Prins reaction. Part 2: Application of organocatalysts in Baylis-Hillman reaction and related cycloaddition A highly enantioselective proline catalyzed intramolecular Baylis–Hillman reaction of hept-2-enedial is reported. Addition of imidazole to the mixture results in an unusual inversion of enantioselectivity. The organocatalyzed [3 + 3] and [4+2] cycloaddition of ?β-unsaturated aldehydes affored aromatic aldehydes.
author2 none
author_facet none
Shang-Hong Chen
陳尚鴻
author Shang-Hong Chen
陳尚鴻
spellingShingle Shang-Hong Chen
陳尚鴻
1. Approach to the kempane skeleton via intramolecular Diels-Alder cycloaddition of fulvene 2. Application of organocatalysts in Baylis-Hillman reaction and related cycloaddition
author_sort Shang-Hong Chen
title 1. Approach to the kempane skeleton via intramolecular Diels-Alder cycloaddition of fulvene 2. Application of organocatalysts in Baylis-Hillman reaction and related cycloaddition
title_short 1. Approach to the kempane skeleton via intramolecular Diels-Alder cycloaddition of fulvene 2. Application of organocatalysts in Baylis-Hillman reaction and related cycloaddition
title_full 1. Approach to the kempane skeleton via intramolecular Diels-Alder cycloaddition of fulvene 2. Application of organocatalysts in Baylis-Hillman reaction and related cycloaddition
title_fullStr 1. Approach to the kempane skeleton via intramolecular Diels-Alder cycloaddition of fulvene 2. Application of organocatalysts in Baylis-Hillman reaction and related cycloaddition
title_full_unstemmed 1. Approach to the kempane skeleton via intramolecular Diels-Alder cycloaddition of fulvene 2. Application of organocatalysts in Baylis-Hillman reaction and related cycloaddition
title_sort 1. approach to the kempane skeleton via intramolecular diels-alder cycloaddition of fulvene 2. application of organocatalysts in baylis-hillman reaction and related cycloaddition
publishDate 2006
url http://ndltd.ncl.edu.tw/handle/51860899827903256040
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