Synthesis and Investigation of Chiral Induction Property of Chiral Secondary Amine:6,7-Dihydro-1,2,3- Trimethoxy-5-Phenyl-bis-Benzo[c]Azepin

碩士 === 國立東華大學 === 化學系 === 93 === This thesis describes about the synthesis and investigation of chiral induction property of chiral secondary amine. Using 3,4,5-trimethoxy-benzaldehyde as starting material, via Suzuki coupling and intramolecular Aza-Wittig reaction obtains the target molecule (A) ea...

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Main Authors: Deng-Yi Huang, 黃鐙毅
Other Authors: Tomas Y. R. Tsai
Format: Others
Language:zh-TW
Published: 2005
Online Access:http://ndltd.ncl.edu.tw/handle/90825822820446295736
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spelling ndltd-TW-093NDHU50650222016-06-06T04:11:19Z http://ndltd.ncl.edu.tw/handle/90825822820446295736 Synthesis and Investigation of Chiral Induction Property of Chiral Secondary Amine:6,7-Dihydro-1,2,3- Trimethoxy-5-Phenyl-bis-Benzo[c]Azepin 掌性二級胺類化合物的合成與研究 Deng-Yi Huang 黃鐙毅 碩士 國立東華大學 化學系 93 This thesis describes about the synthesis and investigation of chiral induction property of chiral secondary amine. Using 3,4,5-trimethoxy-benzaldehyde as starting material, via Suzuki coupling and intramolecular Aza-Wittig reaction obtains the target molecule (A) easily. The compound (A) react with carbonyl compound to form the enamine intermediate which can catalyze several asymmetric reactions, such as asymmetric enamine alkylation, aldol reaction, Michael addition and etc. Tomas Y. R. Tsai 蔡英仁 2005 學位論文 ; thesis 120 zh-TW
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language zh-TW
format Others
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description 碩士 === 國立東華大學 === 化學系 === 93 === This thesis describes about the synthesis and investigation of chiral induction property of chiral secondary amine. Using 3,4,5-trimethoxy-benzaldehyde as starting material, via Suzuki coupling and intramolecular Aza-Wittig reaction obtains the target molecule (A) easily. The compound (A) react with carbonyl compound to form the enamine intermediate which can catalyze several asymmetric reactions, such as asymmetric enamine alkylation, aldol reaction, Michael addition and etc.
author2 Tomas Y. R. Tsai
author_facet Tomas Y. R. Tsai
Deng-Yi Huang
黃鐙毅
author Deng-Yi Huang
黃鐙毅
spellingShingle Deng-Yi Huang
黃鐙毅
Synthesis and Investigation of Chiral Induction Property of Chiral Secondary Amine:6,7-Dihydro-1,2,3- Trimethoxy-5-Phenyl-bis-Benzo[c]Azepin
author_sort Deng-Yi Huang
title Synthesis and Investigation of Chiral Induction Property of Chiral Secondary Amine:6,7-Dihydro-1,2,3- Trimethoxy-5-Phenyl-bis-Benzo[c]Azepin
title_short Synthesis and Investigation of Chiral Induction Property of Chiral Secondary Amine:6,7-Dihydro-1,2,3- Trimethoxy-5-Phenyl-bis-Benzo[c]Azepin
title_full Synthesis and Investigation of Chiral Induction Property of Chiral Secondary Amine:6,7-Dihydro-1,2,3- Trimethoxy-5-Phenyl-bis-Benzo[c]Azepin
title_fullStr Synthesis and Investigation of Chiral Induction Property of Chiral Secondary Amine:6,7-Dihydro-1,2,3- Trimethoxy-5-Phenyl-bis-Benzo[c]Azepin
title_full_unstemmed Synthesis and Investigation of Chiral Induction Property of Chiral Secondary Amine:6,7-Dihydro-1,2,3- Trimethoxy-5-Phenyl-bis-Benzo[c]Azepin
title_sort synthesis and investigation of chiral induction property of chiral secondary amine:6,7-dihydro-1,2,3- trimethoxy-5-phenyl-bis-benzo[c]azepin
publishDate 2005
url http://ndltd.ncl.edu.tw/handle/90825822820446295736
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