Membrane Gas Absorption System for Nitric Oxides Removal

碩士 === 淡江大學 === 化學工程與材料工程學系 === 92 === In view of the high cost and gradually strict environmental protection demands for nitric oxides air pollutants, absorption by water or nitric acid aqueous solutions containing oxidative additives using hollow-fiber membrane modules might be a feasible measures...

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Main Authors: Hsiu-Tung Liu, 劉修東
Other Authors: Hsuan Chang
Format: Others
Language:zh-TW
Published: 2004
Online Access:http://ndltd.ncl.edu.tw/handle/61026330263740467177
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spelling ndltd-TW-092TKU000630262016-06-15T04:16:51Z http://ndltd.ncl.edu.tw/handle/61026330263740467177 Membrane Gas Absorption System for Nitric Oxides Removal 薄膜氣體吸收系統去除氮氧化物之研究 Hsiu-Tung Liu 劉修東 碩士 淡江大學 化學工程與材料工程學系 92 In view of the high cost and gradually strict environmental protection demands for nitric oxides air pollutants, absorption by water or nitric acid aqueous solutions containing oxidative additives using hollow-fiber membrane modules might be a feasible measures. Through mathematical simulation and experiments, the feasibility and characteristics of the system are investigated in this thesis. Based on basic principles, mass transfers with chemical reactions of gas phase, membrane phase and liquid phase are modeled for a system where the additive is hydrogen peroxide. An isothermal system using a hydrophobic polypropylene hollow-fiber membrane module is set up for studying the effects of system parameters experimentally. For the waste gas with nitric oxides of 1,200ppm with a 50% oxidation ratio, the nitric oxides absorption efficiency is about 70%. Experimental results are used to determine the effective mass transfer coefficients for those nitric oxides compounds involving chemical absorption. For power plant flue gases, due to the low oxidation ratio, which is about 10%, the absorption efficiency is only about 20% even though high membrane area is used. For nitric oxides gas absorption, the advantage of membrane system lies mainly on the reduction of equipment size. To raise the absorption efficiency relies on the increase of oxidation ratio. Hsuan Chang 張煖 2004 學位論文 ; thesis 97 zh-TW
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description 碩士 === 淡江大學 === 化學工程與材料工程學系 === 92 === In view of the high cost and gradually strict environmental protection demands for nitric oxides air pollutants, absorption by water or nitric acid aqueous solutions containing oxidative additives using hollow-fiber membrane modules might be a feasible measures. Through mathematical simulation and experiments, the feasibility and characteristics of the system are investigated in this thesis. Based on basic principles, mass transfers with chemical reactions of gas phase, membrane phase and liquid phase are modeled for a system where the additive is hydrogen peroxide. An isothermal system using a hydrophobic polypropylene hollow-fiber membrane module is set up for studying the effects of system parameters experimentally. For the waste gas with nitric oxides of 1,200ppm with a 50% oxidation ratio, the nitric oxides absorption efficiency is about 70%. Experimental results are used to determine the effective mass transfer coefficients for those nitric oxides compounds involving chemical absorption. For power plant flue gases, due to the low oxidation ratio, which is about 10%, the absorption efficiency is only about 20% even though high membrane area is used. For nitric oxides gas absorption, the advantage of membrane system lies mainly on the reduction of equipment size. To raise the absorption efficiency relies on the increase of oxidation ratio.
author2 Hsuan Chang
author_facet Hsuan Chang
Hsiu-Tung Liu
劉修東
author Hsiu-Tung Liu
劉修東
spellingShingle Hsiu-Tung Liu
劉修東
Membrane Gas Absorption System for Nitric Oxides Removal
author_sort Hsiu-Tung Liu
title Membrane Gas Absorption System for Nitric Oxides Removal
title_short Membrane Gas Absorption System for Nitric Oxides Removal
title_full Membrane Gas Absorption System for Nitric Oxides Removal
title_fullStr Membrane Gas Absorption System for Nitric Oxides Removal
title_full_unstemmed Membrane Gas Absorption System for Nitric Oxides Removal
title_sort membrane gas absorption system for nitric oxides removal
publishDate 2004
url http://ndltd.ncl.edu.tw/handle/61026330263740467177
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