共軛硝基烯類與有機硼及有機鋁試劑反應之探討

碩士 === 國立臺灣師範大學 === 化學研究所 === 92 === Reaction of nitrile oxides 1a-1n with triethylborane under the open system undergo free radical addition reaction to generate oxime. The mechanism is proposed to be a free-radical reaction via ethyl radical addition and then undergo protonlysis in aque...

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Main Authors: Yih-Ru Wu, 吳易儒
Other Authors: Ching-Fa Yao
Format: Others
Language:zh-TW
Published: 2004
Online Access:http://ndltd.ncl.edu.tw/handle/15733094352784935723
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spelling ndltd-TW-092NTNU00650432015-10-13T13:27:19Z http://ndltd.ncl.edu.tw/handle/15733094352784935723 共軛硝基烯類與有機硼及有機鋁試劑反應之探討 Yih-Ru Wu 吳易儒 碩士 國立臺灣師範大學 化學研究所 92 Reaction of nitrile oxides 1a-1n with triethylborane under the open system undergo free radical addition reaction to generate oxime. The mechanism is proposed to be a free-radical reaction via ethyl radical addition and then undergo protonlysis in aqueous solution. The reaction is stimulated by the presence of oxygen and is also retarded or inhibited by the presence of galvinoxyl in the solution. Ching-Fa Yao 姚清發 2004 學位論文 ; thesis 136 zh-TW
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language zh-TW
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description 碩士 === 國立臺灣師範大學 === 化學研究所 === 92 === Reaction of nitrile oxides 1a-1n with triethylborane under the open system undergo free radical addition reaction to generate oxime. The mechanism is proposed to be a free-radical reaction via ethyl radical addition and then undergo protonlysis in aqueous solution. The reaction is stimulated by the presence of oxygen and is also retarded or inhibited by the presence of galvinoxyl in the solution.
author2 Ching-Fa Yao
author_facet Ching-Fa Yao
Yih-Ru Wu
吳易儒
author Yih-Ru Wu
吳易儒
spellingShingle Yih-Ru Wu
吳易儒
共軛硝基烯類與有機硼及有機鋁試劑反應之探討
author_sort Yih-Ru Wu
title 共軛硝基烯類與有機硼及有機鋁試劑反應之探討
title_short 共軛硝基烯類與有機硼及有機鋁試劑反應之探討
title_full 共軛硝基烯類與有機硼及有機鋁試劑反應之探討
title_fullStr 共軛硝基烯類與有機硼及有機鋁試劑反應之探討
title_full_unstemmed 共軛硝基烯類與有機硼及有機鋁試劑反應之探討
title_sort 共軛硝基烯類與有機硼及有機鋁試劑反應之探討
publishDate 2004
url http://ndltd.ncl.edu.tw/handle/15733094352784935723
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