Coordination Chemistry of Copper(II) and Nickel(II) Macorcyclic Compelexes and Chemical Education

• Main Author: 王柏森
• Other Authors: 鍾崇燊
• Format: Others
• Language: zh-TW
• Published: 2004
• Online Access: http://ndltd.ncl.edu.tw/handle/2g44yg

碩士 === 國立清華大學 === 化學系 === 92 === Abstract Two macrocyclic ligands , 1,4,7,11-Tetraazacyclotetra decane and 3-[8-（2-Cyano-ethyl）-3,5,7,7,10,12,14,14 -octamethyl-1,4,8,11tetraaza-cyclotetradec-1-yl]-propionitrile,two macrocyclic transition metal complexes , cis-Diaqua(1,4,7,11-Tetraazacyclotetradecane) nickel(II) Chorideand {3-[8-（2-Cyano-ethyl）-3,5,7,7,10,12,14,14-octamethyl-1,4,8,11tetraaza-cyclotetradec-1-yl] -propionitrile-N，N，N，N，}corpper(II) Choride , have been prepared. The crystal structures of these two complexes have been determined by X-ray diffraction. Three articles were finished in these two years: 1. Chen Hao Chen Mei Ling Cheng Po Sen Wang Cho Ying Lu Yi Hsuan Li Cheng Shao Cheng Te Ming Chiang Meng Yun Chen Hsin Ying Peng Pin Chien Huang Chung-Sun Chung”Applying an Experimental Method of Instruction to Enhance Senior High School Student，Creativites in Chemistry.” Chemistry, 2003, 61, pp.551-560. 2. Sheng Kang Chang Po Sen Wang Cho Ying Lu Yi Hsuan Li Te Ming Chiang Meng Yun Chen Hsin Ying Peng Pin Chien Huang Chung-Sun Chung “Applying Champagne and Bunce，s Learning-theory Based Science Teaching Method To Enhance Senior High School Students, Creativities in Chemistry ：Millikan oil-drop experiment.” 3. Yung-Jan Lin, Po-Son Wang, Tarun Kumar Misra, Chung-Sun Chung “Kinetic studies of the conversion of to the square planar complex。”