Multi-nuclear One and Two Dimensional Solid State NMR Studies of Bis(2-Methyl-8-Quinolinolato)-(2,6-Dimethylphenolate)Aluminum

• Main Authors: Kun-ta Li, 李昆達
• Other Authors: none
• Format: Others
• Language: zh-TW
• Published: 2004
• Online Access: http://ndltd.ncl.edu.tw/handle/96766117915267682098

碩士 === 國立中山大學 === 化學系研究所 === 92 === Bis(2-methyl-8-quinolinolato)-(2,6-dimethylphenolate)aluminum is a newly synthesized material suitable for manufacturing organic light-emitting devices (OLED). NMR parameters such as chemical shift, dipolar and quadrupolar tensors are intimately related to the electronic and geometric structures which are important for understanding its physical and chemical properties. In this work, we report the solid state NMR studies of this material. By using two-field (corresponding to proton resonance frequencies of 200 MHz, 500 MHz , respectively) 1D 1H MAS, 27Al MAS, 1H/13C CP/MAS and 2D 13C nutation MAS techniques, the chemical shift tensors of 13C and quadrupolar coupling constant of 27Al have been obtained. The relationship between these values and the light-emitting properties of this material is discussed.