Iodine-Induced Cyclization of the Adducts of Dihydropyranones with Cyclopentadiene

碩士 === 國立交通大學 === 應用化學系 === 91 === We systemically further discuss Diels-Alder reaction adducts (7-9) from pyranone derivatives and cyclopentadiene undergo iodolactonization , the stereoselective in this reaction is very high . Because the stereoselective is very high in the re...

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Bibliographic Details
Main Author: 洪豪志
Other Authors: Hsien-Jen Wu
Format: Others
Language:zh-TW
Published: 2003
Online Access:http://ndltd.ncl.edu.tw/handle/52127492447744682123
Description
Summary:碩士 === 國立交通大學 === 應用化學系 === 91 === We systemically further discuss Diels-Alder reaction adducts (7-9) from pyranone derivatives and cyclopentadiene undergo iodolactonization , the stereoselective in this reaction is very high . Because the stereoselective is very high in the reaction which adducts (7-9) undergo iodolactonization , further we want to discuss compound (7-9) derivatives, as compound (25、26), which stereoselective is high or not in iodolactonization . Discuss the Diels-Alder reaction when Lewis acid present .