Synthesis and Structures of Divalent Metal SaltsContaining N,N´-di(6-methyl-2-pyridyl)oxamide

Synthesis and Structures of Divalent Metal SaltsContaining N,N´-di(6-methyl-2-pyridyl)oxamide

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碩士 === 中原大學 === 化學研究所 === 91 === Abstract This thesis discusses the supramolecular chemistry of divalent metal Salts containing protonated N,N´-di(6-methyl-2-pyridyl)oxamide. Their structures have been determined by X-ray crystallography and characterized by FT-IR, 1H NMR, TGA and DSC. The react...

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Main Authors: Yueh-lan Wang, 王月蘭
Other Authors: Jhy-Der Chen
Format: Others
Language:zh-TW
Published: 2003
Online Access:http://ndltd.ncl.edu.tw/handle/56154190379259327819
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spelling ndltd-TW-091CYCU50650302015-10-13T16:56:49Z http://ndltd.ncl.edu.tw/handle/56154190379259327819 Synthesis and Structures of Divalent Metal SaltsContaining N,N´-di(6-methyl-2-pyridyl)oxamide 含N,N´-二-(6-甲基-2-吡啶)乙二醯二胺之二價金屬鹽類的合成與結構研究 Yueh-lan Wang 王月蘭 碩士 中原大學 化學研究所 91 Abstract This thesis discusses the supramolecular chemistry of divalent metal Salts containing protonated N,N´-di(6-methyl-2-pyridyl)oxamide. Their structures have been determined by X-ray crystallography and characterized by FT-IR, 1H NMR, TGA and DSC. The reactions of the divalent metal halides with N, N´-di(6-methyl-2-pyridyl)oxamide and HCl afforded the following complexes: (H2DMePyO)(NO3)2，1；(SnCl6)(HMe-2-Amp)2，2；(CdCl4)2(H2DMe PyO)(HMe-2-Amp)2，3；(ZnCl4)2(H2DMePyO)(HMe-2-Amp) ，4； (HgCl4)2(H2DMePyO)(HMe-2-Amp)2，5。 In these complexes, extensive M-X---H-Y (M = metal; X = Cl or Br; Y = N or C) hydrogen bondings are used to link the metal units to the protonated N,N´-di(6-methyl-2-pyridyl)oxamide Jhy-Der Chen 陳志德 2003 學位論文 ; thesis 86 zh-TW
collection NDLTD
language zh-TW
format Others
sources NDLTD
description 碩士 === 中原大學 === 化學研究所 === 91 === Abstract This thesis discusses the supramolecular chemistry of divalent metal Salts containing protonated N,N´-di(6-methyl-2-pyridyl)oxamide. Their structures have been determined by X-ray crystallography and characterized by FT-IR, 1H NMR, TGA and DSC. The reactions of the divalent metal halides with N, N´-di(6-methyl-2-pyridyl)oxamide and HCl afforded the following complexes: (H2DMePyO)(NO3)2，1；(SnCl6)(HMe-2-Amp)2，2；(CdCl4)2(H2DMe PyO)(HMe-2-Amp)2，3；(ZnCl4)2(H2DMePyO)(HMe-2-Amp) ，4； (HgCl4)2(H2DMePyO)(HMe-2-Amp)2，5。 In these complexes, extensive M-X---H-Y (M = metal; X = Cl or Br; Y = N or C) hydrogen bondings are used to link the metal units to the protonated N,N´-di(6-methyl-2-pyridyl)oxamide
author2 Jhy-Der Chen
author_facet Jhy-Der Chen
Yueh-lan Wang
王月蘭
author Yueh-lan Wang
王月蘭
spellingShingle Yueh-lan Wang
王月蘭
Synthesis and Structures of Divalent Metal SaltsContaining N,N´-di(6-methyl-2-pyridyl)oxamide
author_sort Yueh-lan Wang
title Synthesis and Structures of Divalent Metal SaltsContaining N,N´-di(6-methyl-2-pyridyl)oxamide
title_short Synthesis and Structures of Divalent Metal SaltsContaining N,N´-di(6-methyl-2-pyridyl)oxamide
title_full Synthesis and Structures of Divalent Metal SaltsContaining N,N´-di(6-methyl-2-pyridyl)oxamide
title_fullStr Synthesis and Structures of Divalent Metal SaltsContaining N,N´-di(6-methyl-2-pyridyl)oxamide
title_full_unstemmed Synthesis and Structures of Divalent Metal SaltsContaining N,N´-di(6-methyl-2-pyridyl)oxamide
title_sort synthesis and structures of divalent metal saltscontaining n,n´-di(6-methyl-2-pyridyl)oxamide
publishDate 2003
url http://ndltd.ncl.edu.tw/handle/56154190379259327819
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AT wángyuèlán hánnnèr6jiǎjī2bǐdìngyǐèrxīèrànzhīèrjiàjīnshǔyánlèidehéchéngyǔjiégòuyánjiū
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