Synthesis of Rigid Molecules for Investigations of Photoinduced Electron Transfer Rate
碩士 === 國立臺灣大學 === 化學研究所 === 90 === Electron transfer rate in Donor - Spacer - Acceptor (DSA) molecules in a series of oligonorbornane significantly increased our understanding on the factors that control electron transfer. The synthesis of symmetrical oligonorborane- based DSA molecules...
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| Format: | Others |
| Language: | zh-TW |
| Published: |
2002
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| Online Access: | http://ndltd.ncl.edu.tw/handle/24678002872541007630 |
| Summary: | 碩士 === 國立臺灣大學 === 化學研究所 === 90 === Electron transfer rate in Donor - Spacer - Acceptor (DSA) molecules in a series of oligonorbornane significantly increased our understanding on the factors that control electron transfer. The synthesis of symmetrical oligonorborane- based DSA molecules are described. These molecules are used to explore the effects of molecular geometry on photoinduced electron transfer rate. In compound (9 ) the fluorescence of naphthalene is quenched 94% by acceptor, where in compound (10) it is quenched 35% .
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