Synthesis and Anion-Selective Complexation of Ferrocenecarbamide Derivatives

碩士 === 國立臺灣大學 === 化學研究所 === 90 === As a result of the biological and environmental significance of anions, selective recognition and sensing of anions are of great importance in modern host-guest chemistry. It is known that the amido protons can serve as hydrogen-bond donors for acetate,...

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Main Authors: Kuo, Li-Jun, 郭麗君
Other Authors: Fang, Jim-Min
Format: Others
Language:zh-TW
Published: 2002
Online Access:http://ndltd.ncl.edu.tw/handle/22205257128405006131
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spelling ndltd-TW-090NTU000650142015-10-13T14:38:05Z http://ndltd.ncl.edu.tw/handle/22205257128405006131 Synthesis and Anion-Selective Complexation of Ferrocenecarbamide Derivatives 合成二茂鐵醯胺類衍生物及與陰離子選擇性錯合之研究 Kuo, Li-Jun 郭麗君 碩士 國立臺灣大學 化學研究所 90 As a result of the biological and environmental significance of anions, selective recognition and sensing of anions are of great importance in modern host-guest chemistry. It is known that the amido protons can serve as hydrogen-bond donors for acetate, nitrate, fluoride and dihydrogenphosphate ions. In this thesis, we synthesized a series of artificial neutral anion receptors with multiple amide scaffolds. The structure was established by incorporating four additional amido groups to the main skeleton of ferrocene 2,6-biscarboxamide. From 1H NMR spectroscopy, we found that our synthetic receptors bound H2PO4- anions most strongly. The binding properties of these receptors with H2PO4- anions were evaluated by the 1H NMR studies in DMSO-d6 solutions. The 1:1 complexation stoichiometry of receptors 8, 12, 15 with H2PO4- anions and the 1:2 complexation stoichiometry of receptors 7, 11, 16 with H2PO4- anions were confirmed by a continuous variation method (Job’s plot). We also found that receptors 11 and 12 bearing electron-withdrawing groups can act as better H2PO4- receptors. Optical and redox properties of these receptors were assessed by fluorescence measurements and cyclic voltammetry. Fang, Jim-Min 方俊民 2002 學位論文 ; thesis 135 zh-TW
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language zh-TW
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description 碩士 === 國立臺灣大學 === 化學研究所 === 90 === As a result of the biological and environmental significance of anions, selective recognition and sensing of anions are of great importance in modern host-guest chemistry. It is known that the amido protons can serve as hydrogen-bond donors for acetate, nitrate, fluoride and dihydrogenphosphate ions. In this thesis, we synthesized a series of artificial neutral anion receptors with multiple amide scaffolds. The structure was established by incorporating four additional amido groups to the main skeleton of ferrocene 2,6-biscarboxamide. From 1H NMR spectroscopy, we found that our synthetic receptors bound H2PO4- anions most strongly. The binding properties of these receptors with H2PO4- anions were evaluated by the 1H NMR studies in DMSO-d6 solutions. The 1:1 complexation stoichiometry of receptors 8, 12, 15 with H2PO4- anions and the 1:2 complexation stoichiometry of receptors 7, 11, 16 with H2PO4- anions were confirmed by a continuous variation method (Job’s plot). We also found that receptors 11 and 12 bearing electron-withdrawing groups can act as better H2PO4- receptors. Optical and redox properties of these receptors were assessed by fluorescence measurements and cyclic voltammetry.
author2 Fang, Jim-Min
author_facet Fang, Jim-Min
Kuo, Li-Jun
郭麗君
author Kuo, Li-Jun
郭麗君
spellingShingle Kuo, Li-Jun
郭麗君
Synthesis and Anion-Selective Complexation of Ferrocenecarbamide Derivatives
author_sort Kuo, Li-Jun
title Synthesis and Anion-Selective Complexation of Ferrocenecarbamide Derivatives
title_short Synthesis and Anion-Selective Complexation of Ferrocenecarbamide Derivatives
title_full Synthesis and Anion-Selective Complexation of Ferrocenecarbamide Derivatives
title_fullStr Synthesis and Anion-Selective Complexation of Ferrocenecarbamide Derivatives
title_full_unstemmed Synthesis and Anion-Selective Complexation of Ferrocenecarbamide Derivatives
title_sort synthesis and anion-selective complexation of ferrocenecarbamide derivatives
publishDate 2002
url http://ndltd.ncl.edu.tw/handle/22205257128405006131
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