Spectroscopic Study of the NaH C1S＋Higher and Lower Vibrational State Levels
碩士 === 國立成功大學 === 化學系碩博士班 === 90 === In this study, nineteen vibrational levels of the NaH C1□＋ electronic state have been observed by the Optical-Optical Double Resonance Fluorescence Depletion Spectroscopy (OODR-FDS) technique. We applied the stepwise OODR excitation in our experiments. The OODR...
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| Format: | Others |
| Language: | zh-TW |
| Published: |
2002
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| Online Access: | http://ndltd.ncl.edu.tw/handle/09806270925591292854 |
| Summary: | 碩士 === 國立成功大學 === 化學系碩博士班 === 90 ===
In this study, nineteen vibrational levels of the NaH C1□＋ electronic state have been observed by the Optical-Optical Double Resonance Fluorescence Depletion Spectroscopy (OODR-FDS) technique. We applied the stepwise OODR excitation in our experiments. The OODR spectra of the NaH C1□＋ electronic state have been taken by monitoring the fluorescence depletion of the A1□＋ state to the X1□＋ state.
We have observed 223 rovibrational levels (including 19 vibrational levels) of the C1□＋ electronic state, they are in the range of 36690 ~ 41500 cm-1. The observed vibrational level spacings of ΔGv＋1/2 are in the range 189 ~ 89 cm-1and derived rotational constants Bv are 0.488 ~ 0.636 cm-1.
However, we have to confirm the absolute vibrational quantum number by a further study and the Dunham coefficients can be derived to construct the complete potential energy curve of the NaH C1□＋ electronic state.
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