Ligand Effect on Insertion of Unsaturated Substrates into Pd-C Bonds

碩士 === 國立臺灣大學 === 化學研究所 === 89 === Palladium(II) catalyzed polymerization and copolymerization of olefins and carbon monoxide is one of the active areas of current research. The active catalysts are the square planar [Pd(L-L)(R)(L’)] complexes, where L-L is either bidentate phosphines (P-...

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Main Authors: Docomo Hsu, 許平源
Other Authors: Shiuh-Tzung Liu
Format: Others
Language:zh-TW
Published: 2001
Online Access:http://ndltd.ncl.edu.tw/handle/35357156717875631253
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spelling ndltd-TW-089NTU000650742016-07-04T04:17:54Z http://ndltd.ncl.edu.tw/handle/35357156717875631253 Ligand Effect on Insertion of Unsaturated Substrates into Pd-C Bonds 多牙配位基對鈀金屬錯合物在烯類及一氧化碳嵌入與聚合反應之影響 Docomo Hsu 許平源 碩士 國立臺灣大學 化學研究所 89 Palladium(II) catalyzed polymerization and copolymerization of olefins and carbon monoxide is one of the active areas of current research. The active catalysts are the square planar [Pd(L-L)(R)(L’)] complexes, where L-L is either bidentate phosphines (P-P) or diimines (N-N) ligands and L’ is generally a weak coordinated ligand viz., acetonitrile or ether. Our lab is currently working on dissymmetric phosphine-imine donor ligands. A new P-N-O tridentate ligand and its palladium complex is prepared. Insertion as well as polymerization studies with olefins or carbon monoxide were carried out. Shiuh-Tzung Liu 劉緒宗 2001 學位論文 ; thesis 108 zh-TW
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language zh-TW
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description 碩士 === 國立臺灣大學 === 化學研究所 === 89 === Palladium(II) catalyzed polymerization and copolymerization of olefins and carbon monoxide is one of the active areas of current research. The active catalysts are the square planar [Pd(L-L)(R)(L’)] complexes, where L-L is either bidentate phosphines (P-P) or diimines (N-N) ligands and L’ is generally a weak coordinated ligand viz., acetonitrile or ether. Our lab is currently working on dissymmetric phosphine-imine donor ligands. A new P-N-O tridentate ligand and its palladium complex is prepared. Insertion as well as polymerization studies with olefins or carbon monoxide were carried out.
author2 Shiuh-Tzung Liu
author_facet Shiuh-Tzung Liu
Docomo Hsu
許平源
author Docomo Hsu
許平源
spellingShingle Docomo Hsu
許平源
Ligand Effect on Insertion of Unsaturated Substrates into Pd-C Bonds
author_sort Docomo Hsu
title Ligand Effect on Insertion of Unsaturated Substrates into Pd-C Bonds
title_short Ligand Effect on Insertion of Unsaturated Substrates into Pd-C Bonds
title_full Ligand Effect on Insertion of Unsaturated Substrates into Pd-C Bonds
title_fullStr Ligand Effect on Insertion of Unsaturated Substrates into Pd-C Bonds
title_full_unstemmed Ligand Effect on Insertion of Unsaturated Substrates into Pd-C Bonds
title_sort ligand effect on insertion of unsaturated substrates into pd-c bonds
publishDate 2001
url http://ndltd.ncl.edu.tw/handle/35357156717875631253
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