the carbon carbon bond formation of allenyl/Propargrl complexes of palladium and platinum

碩士 === 國立臺灣大學 === 化學研究所 === 87 === In Our experiment , we are interested in reaction of η3-Propargyl complexes of platinum and palladium {M(PPh3)2(η3-C3H3)}(BF4), (M = Pd 3 , Pt 4 ), with enaminone (NHR)(Me)C=C(COMe)( R = iPr 5a, Me 5b), leads to the formation of the cationic complexes M{...

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Main Authors:	Sheng Yi CHen, 陳聖宜
Other Authors:	Jwu Ting Chen
Format:	Others
Language:	en_US
Published:	1999
Online Access:	http://ndltd.ncl.edu.tw/handle/38450697094188750942

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spelling	ndltd-TW-087NTU000650242016-02-01T04:12:24Z http://ndltd.ncl.edu.tw/handle/38450697094188750942 the carbon carbon bond formation of allenyl/Propargrl complexes of palladium and platinum 丙二烯基及炔丙基鈀及鉑錯合物的碳碳鍵形成反應 Sheng Yi CHen 陳聖宜碩士國立臺灣大學化學研究所 87 In Our experiment , we are interested in reaction of η3-Propargyl complexes of platinum and palladium {M(PPh3)2(η3-C3H3)}(BF4), (M = Pd 3 , Pt 4 ), with enaminone (NHR)(Me)C=C(COMe)( R = iPr 5a, Me 5b), leads to the formation of the cationic complexes M{η3-CH2 [(COMe)C=C(Me)(NHR)]CH2}(PPh3)2}BF4 (M = Pd 7a 7b, Pt = 8a 8b), via formation of a carbon-carbon bond . After heating the complexes 7,8 , the organic compound pyrrole is appeared according to organic ring formation. Jwu Ting Chen 陳竹亭 1999 學位論文 ; thesis 105 en_US
collection	NDLTD
language	en_US
format	Others
sources	NDLTD
description	碩士 === 國立臺灣大學 === 化學研究所 === 87 === In Our experiment , we are interested in reaction of η3-Propargyl complexes of platinum and palladium {M(PPh3)2(η3-C3H3)}(BF4), (M = Pd 3 , Pt 4 ), with enaminone (NHR)(Me)C=C(COMe)( R = iPr 5a, Me 5b), leads to the formation of the cationic complexes M{η3-CH2 [(COMe)C=C(Me)(NHR)]CH2}(PPh3)2}BF4 (M = Pd 7a 7b, Pt = 8a 8b), via formation of a carbon-carbon bond . After heating the complexes 7,8 , the organic compound pyrrole is appeared according to organic ring formation.
author2	Jwu Ting Chen
author_facet	Jwu Ting Chen Sheng Yi CHen 陳聖宜
author	Sheng Yi CHen 陳聖宜
spellingShingle	Sheng Yi CHen 陳聖宜 the carbon carbon bond formation of allenyl/Propargrl complexes of palladium and platinum
author_sort	Sheng Yi CHen
title	the carbon carbon bond formation of allenyl/Propargrl complexes of palladium and platinum
title_short	the carbon carbon bond formation of allenyl/Propargrl complexes of palladium and platinum
title_full	the carbon carbon bond formation of allenyl/Propargrl complexes of palladium and platinum
title_fullStr	the carbon carbon bond formation of allenyl/Propargrl complexes of palladium and platinum
title_full_unstemmed	the carbon carbon bond formation of allenyl/Propargrl complexes of palladium and platinum
title_sort	carbon carbon bond formation of allenyl/propargrl complexes of palladium and platinum
publishDate	1999
url	http://ndltd.ncl.edu.tw/handle/38450697094188750942
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the carbon carbon bond formation of allenyl/Propargrl complexes of palladium and platinum

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