Using Pump-Probe Fluorescence Depletion To Study the Rotationally Resolved Spectra and The J-Dependent Predissociation Rate of CS2
碩士 === 國立臺灣大學 === 物理學系研究所 === 86 === By monitoring single vibronic level pumo-probe fluorescence depletion,T he rotationally resolved spectra of the 46482 cm-1 band of CS2 were recorded.T he molecular constants are V=46481.51(11)cm-1, B=0.09809(24)...
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| Other Authors: | |
| Format: | Others |
| Language: | zh-TW |
| Published: |
1998
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| Online Access: | http://ndltd.ncl.edu.tw/handle/24285143307447085972 |
| Summary: | 碩士 === 國立臺灣大學 === 物理學系研究所 === 86 === By monitoring single vibronic level pumo-probe fluorescence depletion,T
he rotationally resolved spectra of the 46482 cm-1 band of CS2 were recorded.T
he molecular constants are V=46481.51(11)cm-1, B=0.09809(24)cm-1, and D=6.7(9.
3)*10-8 cm-1.The J-dependent predissociation rate was anallyzed. Atlow J level
s the predissociation rate is dominated dy the energy seperation and the coupl
ing between the bound and the repulsive states, where at high J levelsstates t
he rate is controlled by the tunneling though the barrier of the centrifugalpo
tential.
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