Separation of m-chlorophenol+p-chlorophenol by adductive
碩士 === 國立中央大學 === 化學工程學系 === 86 === An adductive crystallization method was employed in this study to separate closing-boiling point m-chlorophenol +p- chlorophenol mixtures in this study. Neutralizing agents including tert-butanol and aniline have bee...
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Other Authors: | |
Format: | Others |
Language: | zh-TW |
Published: |
1998
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Online Access: | http://ndltd.ncl.edu.tw/handle/57537016406933228342 |
Summary: | 碩士 === 國立中央大學 === 化學工程學系 === 86 === An adductive crystallization method was employed in this study
to separate closing-boiling point m-chlorophenol +p-
chlorophenol mixtures in this study. Neutralizing agents
including tert-butanol and aniline have been tested for
separating the mixtures and their applicabilities were
discussed. We found that aniline could be a potential
neutralizing agent by the fact that it forms complexs with both
m-chlorophenol and p-chlorophenol. Consequently,we further
investigated the solid-liquid phase behavior for the ternary
system of aniline +m-chlorophenol +p-chlorophenol. This ternary
phase diagram provided us useful information for finding a
feasible separati- on procedure and favorable operation
conditions. The separating process was disscussed by duffferent
initial composition of m-chlorophenol +p-chlorophenol mixture.
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