New Materials Synthesis from Molybdenum Nitrido Complex

• Main Authors: Lo, Chia-Ping, 羅加聘
• Other Authors: Chiu, Hsin-Tien
• Format: Others
• Language: zh-TW
• Published: 1998
• Online Access: http://ndltd.ncl.edu.tw/handle/69805124718319039174

碩士 === 國立交通大學 === 應用化學研究所 === 86 === 　　Nano-sized powder was prepared by the reaction of N≡Mo(OSiMe3)3Py with tBuLi in n-hexane . The reaction of (NH4)2Mo2O7 with HN(SiMe3)2 yielded [N≡Mo(OSiMe3)3NH3]2. Addition of pyridine and 2,2'-dipyridyl to [N≡Mo(OSiMe3)3NH3]2 resulted the isolation of N≡Mo(OSiMe3)3Py and N≡Mo(OSiMe3)3dipy, respectively, Treatment of N≡Mo(OSiMe3)3Py with Me3SiCl formed and orange-red power, which contained NMoCl3. Addition of LiOtBu to this power resulted N≡Mo(OtBu3)3. Treatment of N≡Mo(OSiMe3)3Py with tBuLi in n-hexane resulted nano-sized power, which contained Mo、N、C、O、Si.