Electric and steric factors affecting the formation of aluminum complexes
碩士 === 國立中興大學 === 化學系 === 86 === 2-苯氧基乙醇與AlX3反應生成高產率的五配位雙體產物[(u-OCH2CH2OPh) AlX2]2(1, X=Cl; 2, X=Br) 錯化合物1屬於斜方晶系,Pbca空間群,錯化合 物2結晶於空間群, 但是當2-苯氧基乙醇與Al(Bui)3 反應卻是生成一個四 配位雙體的產物[(u-O(CH2)2OPh)Al(Bui)2]2 (3), 錯化合物3 屬於三斜 晶系,空間群P-1,...
Main Authors: | Lin, Chia-Her, 林嘉和 |
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Other Authors: | Chu-Chieh Lin |
Format: | Others |
Language: | zh-TW |
Published: |
1998
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Online Access: | http://ndltd.ncl.edu.tw/handle/26303734258917587761 |
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