Ultrasound of Induced Desilylation Triethylsilyl and Triisopropylsilyl enol ethers

碩士 === 淡江大學 === 化學學系 === 84 === Abstract:The transforation of alcohol to its corresponding silyl-ethers is acommon and useual method for protecting hydroxyl group.Herewith,we with to report our results of desilylations without any reagent...

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Bibliographic Details
Main Authors: Yeh, Chong-Ing, 葉瓊霙
Other Authors: Adam Shih Yuan Lee
Format: Others
Language:zh-TW
Published: 1996
Online Access:http://ndltd.ncl.edu.tw/handle/73276374501823517418
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Summary:碩士 === 淡江大學 === 化學學系 === 84 === Abstract:The transforation of alcohol to its corresponding silyl-ethers is acommon and useual method for protecting hydroxyl group.Herewith,we with to report our results of desilylations without any reagent under neutral conditions. Aseries of triethylsilyl ethers (TESOR)、triisopropylsilyl ethers(TIPSOR)、Tert-butyldimethylsilyl ethers(TBDMSOR)、 Tert- butyldi phenylsilyl ethers(TBDPSOR) in a 0.25M CH3OH/CCl4 (1:1) solvent were investigated under ultrasonic reaction condition.