Ultrasound of Induced Desilylation Triethylsilyl and Triisopropylsilyl enol ethers
碩士 === 淡江大學 === 化學學系 === 84 === Abstract:The transforation of alcohol to its corresponding silyl-ethers is acommon and useual method for protecting hydroxyl group.Herewith,we with to report our results of desilylations without any reagent...
Main Authors: | , |
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Other Authors: | |
Format: | Others |
Language: | zh-TW |
Published: |
1996
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Online Access: | http://ndltd.ncl.edu.tw/handle/73276374501823517418 |
Summary: | 碩士 === 淡江大學 === 化學學系 === 84 === Abstract:The transforation of alcohol to its corresponding
silyl-ethers is acommon and useual method for protecting
hydroxyl group.Herewith,we with to report our results of
desilylations without any reagent under neutral conditions.
Aseries of triethylsilyl ethers (TESOR)、triisopropylsilyl
ethers(TIPSOR)、Tert-butyldimethylsilyl ethers(TBDMSOR)、 Tert-
butyldi phenylsilyl ethers(TBDPSOR) in a 0.25M CH3OH/CCl4 (1:1)
solvent were investigated under ultrasonic reaction condition.
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