| Summary: | 博士 === 國立臺灣大學 === 化學學系 === 84 === Reaction between ketone complex 9 and Wittig reagent in THF
yield ed alkene complex 11. Reactions of 9 with MeLi, nBuLi, or
sBuLi following with CH3OH produced alcohol complexes 10, 13,
24, respe ctively, which were converted to the alkene complexes
11, 14, 25 by dehydration. Imine complexes 32, 33, 34, 35, 36
had been prepa red by the ketone complex 9 with various primary
amines. The acet yl group of the complex 9 reacted with LDA in
THF at -78 ℃ to yi eld enolated anion 16, which reacted with
alkane halides to produ ce two species derivatives, one species
were C-alkylation complex es 17, 20, 21, 22, the other were O-
alkylation complexes 18, 19. The dimetal complexes 28, 29 were
formed from the enolated anion 16 with electrophilic metal
complexes CpFe(CO)2I and [CpW(CO)3(CH 3CN)]BF4.
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