A classical trajectory study of the three dimensional Cl + HOD → HCl + OD reaction
碩士 === 輔仁大學 === 化學系 === 84 === We consider various initial conditions for the translational energy, normalmode excitation of HOD and rotational energy of HOD.We find that excitation of the asymmetric stretch increase the cross sectionmore t...
| Main Authors: | , |
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| Other Authors: | |
| Format: | Others |
| Language: | zh-TW |
| Published: |
1996
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| Online Access: | http://ndltd.ncl.edu.tw/handle/07001989054692385672 |
| Summary: | 碩士 === 輔仁大學 === 化學系 === 84 === We consider various initial conditions for the translational
energy, normalmode excitation of HOD and rotational energy of
HOD.We find that excitation of the asymmetric stretch increase
the cross sectionmore than excitation of bending mode. The
symmetric stretch does not jointhis reaction much. The initial
asymmetric stretch energy transfers to theproduct H-Cl bond, the
translational energy increase the cross section, theinitial
rotational motion has little effect on the cross section nor on
the final energy distribution of the products.
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