Mechanistic Study of Nucleophilic Addition of Amine to Octahedral Iridium η1-Allenyl Leading to η3-Azatrimethylenemethane Derivatives
碩士 === 國立臺灣大學 === 化學學系 === 83 === Oxidative-addition of propargyl halides to the Vaska complex yielded neutral octahedral allenyl complexes Ir(η1-CH=C=CH2)(CO)(Cl)2(PPh3)2 1a , Ir(η1-CH=C=CH2)(CO)(Br)(Cl)(PPh3)2 1b, Ir(ηCH=C=CH2)(CO)(Br)(Cl)(PPh3)2 1c. Treatment of 1b with AgOTf resulted Ir(η1-...
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| Format: | Others |
| Language: | zh-TW |
| Published: |
1995
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| Online Access: | http://ndltd.ncl.edu.tw/handle/14031800758949910908 |