Tricarbonyliron Triene Complexes As Versatile Synthetic Intermediate

• Main Authors: Chien, Ting-Lin, 簡廷燐
• Other Authors: Ong, Chi Wi
• Format: Others
• Language: zh-TW
• Published: 1995
• Online Access: http://ndltd.ncl.edu.tw/handle/29201121273100930729

碩士 === 國立中山大學 === 化學學系 === 83 === Organoiron complexes are readily available and can serve as starting meterials for the synthesis of numerous natural products. The synthetic applications of the tricarbonyliron triene complexes not been explored previously. The organic compound, 1-methylene-4-methoxycyclohex-2,4- diene, does not exist which will tautomerized rapidly to 4-methylanisole. The Fe(CO)3 act as a protecting and stabilizing group for the exocyclic methylene group and this has important synthetic applications. We now proposed to carry out new chemical and stereochemistry applications of a new series of organoiron complex. (1) Electrophilic substitution reaction , including trapping with nucleophiles. (2) 1,3-Dipolar cycloaddition reactions.