| Summary: | 碩士 === 國立臺灣科技大學 === 纖維工程技術系 === 82 === This thesis discusses the synthesis of Matal phthalocyanine
sheet polymers were prepared by the reaction of
3,3',4,4'-benzophenonetetracarboxylic dianhydride , metal ( Co,
Cu and Zn ) salt,urea and catalyst at 150∼250℃.UV/VIS
spectrum,IR spectrum , elemetal analysis , X-ray diffraction
, theral analysis(TGA and DTG) and conductivity measurement
were carried out for the characterization. There materials
have green or deep blue color and only soluble in sulfuric
acide.The UV/VIS spectrum shows three or four peaks.X-ray
diffraction shows two peaks and amorphous, The elemetal
analysis indicated 10∼30 degree of polymization were
occured, the TGA studies inducate exellent thermal stability
in nitrogen atmosphere and thermal oxidative stability
in air. At last the conductivity measurements show that
conductivities are about 10-9 Ω-1 cm-1 at room temperature
and increase conductivity from 10-9 Ω-1 cm-1 to 10-6
Ω-1 cm-1 with temperature. These results indicate that
these materials are semiconductor in nature.
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