Study on An Electrolysis oxidation of Dye Solution by Carbon Fiber Electrode

碩士 === 國立中央大學 === 化學工程研究所 === 82 === When use electrochemical treatment in the decolorization dyeing effluent, it was always operated with metal as a cathode. The metal cathode would react and dissolve in dyeing effluent. The metal ion which was conta...

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Bibliographic Details
Main Authors: Jang-Jong Din, 丁建中
Other Authors: Kung-Tu Kuo
Format: Others
Language:zh-TW
Published: 1994
Online Access:http://ndltd.ncl.edu.tw/handle/71601869447369104339
Description
Summary:碩士 === 國立中央大學 === 化學工程研究所 === 82 === When use electrochemical treatment in the decolorization dyeing effluent, it was always operated with metal as a cathode. The metal cathode would react and dissolve in dyeing effluent. The metal ion which was contained in effluent is another pollution and increases the amount of sludge. The research use carbon fiber and stainless steel as a cathode and an anode. The equipment can be successful in remov- ing the color of dye from aqueous solution and don`t increase any sacond pollution. But this methode remove organic carbon very slowly. Following experiment, organic carbon were removed 16% during 90 minutes, but the dye was decomposed during 30 minutes. In order to research the reaction of electrolysis and mechanism of color- removing, choose H-type tube to treat dye solution. Then cell was operated in batch mode to understand the variables of operation (example:concentration of electro- lyte, concentraion of dye solution, voltage and pH value of initial dye solution, etc. ) and the effect of electrochemical treatment. Applying the above result operate cell of flowing cyclization mode. Cell of flowing cyclization mode can treat large amount of dye solution but the flow rate of dye solution must fit other operated condition. Following experiment, when the flow rate of dye solution were 30 and 50 ml/min, the decolor amount of per coulomb were 0.3 and 0.05mg.