Synthesis of AlPO4-5 and the elimination of alcohol from acetaldehydedimethyl acetal

碩士 === 國立中央大學 === 化學工程研究所 === 82 === This study includes two parts. In the first part, We try to synthesis uniform large crystal of AlPO4-5 for materials application, and study each parameter on the influence of growing To obtain large and...

Full description

Bibliographic Details
Main Authors: G.T.Wang, 王國鎮
Other Authors: Sze-Ming Yang
Format: Others
Language:zh-TW
Published: 1994
Online Access:http://ndltd.ncl.edu.tw/handle/27302088186728219769
Description
Summary:碩士 === 國立中央大學 === 化學工程研究所 === 82 === This study includes two parts. In the first part, We try to synthesis uniform large crystal of AlPO4-5 for materials application, and study each parameter on the influence of growing To obtain large and uniform AlPO4-5 by hydrothermal treatment, when gel comopsition:(C2H5)N:Al2O3:P2O5: H2)=1.55:1:1:600, aluminua source obtained from hydrosis of pseudo boehmite is better than In the elimination alcohol of acetaldehydedimethyl acetal (DMA),the results reveal that, selectivity over each zeolite catalysts is very high (near 100%),but the aluminaphosplate Under 1 atm , WHSV=27hr-1,With increasing tempature to 250℃,the conversion of AlPO4-5,SAPO-5 is 100%.Strong acid active site helps the double bond products MVE polymerization in large