Synthesis of Pure 80K Bulk Material in Y-Sr-Cu-O System

碩士 === 淡江大學 === 物理研究所 === 81 === In this research the frabrication of 80K phase bulk material of high Tc superconducting Y-Sr-Cu-O system was studied. Solid state reaction method was used. Due to the instability of the structure of 80K phas...

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Bibliographic Details
Main Authors: Gung shaw-yuan, 龔紹淵
Other Authors: Chien F.Z.
Format: Others
Language:zh-TW
Published: 1993
Online Access:http://ndltd.ncl.edu.tw/handle/63370117267843112693
Description
Summary:碩士 === 淡江大學 === 物理研究所 === 81 === In this research the frabrication of 80K phase bulk material of high Tc superconducting Y-Sr-Cu-O system was studied. Solid state reaction method was used. Due to the instability of the structure of 80K phase, doping of Mo atom is needed in the material preparation. Although the structure of 80K phase was identified to be similar to YBCO123 as that of 40k phase, but its chemical composition is Sr-rich and deviated from the proportionality of 1-2-3. The annealing temperature for 80K phase varies from 1050℃ to 1175℃ when the oxygen pressure change from 1x10^-3 torr to 6atm. The best post-annealing condition is at 900℃ and O2 of 1atm.