| Summary: | 碩士 === 國立臺灣科技大學 === 化學工程研究所 === 81 === A falling ball viscometer and pycnometers have been employed to
measure the liquid viscosity and density, respectively. Four
binary and two ternary systems composed of water, butylamine,
benzylamine, and ethanol were investigated at atmospheric
pressure and at 303.15K , 313.15K , 323.15 K. According to the
experiment data, the molecular interations involving in each
system were discussed and the exccess volumes , viscosites as
well as Gibbs free energies were fitted by a variety of
empirical models. The mixing rules of the three-reference-fluid
corresponding- state viscosity model have been improved for
aqueous solutions . It is found that the model with an
augmented asymmetric mixing rule predicts satisfactorily the
viscosity of ternary aqueous solutinns using determined binary
interaction constants . Moreover, an attempt of correlating
solution''s thermophysical data by means of neural networks has
been made. It apperas that the neural networks trained by
characteristic imformation of binary systems can successfully
estimate the viscosity and density for the ternary aqueous
solutions.
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