Applications of α-Keto Carbocations in Carbon-Carbon and Carbon-Nitrogen Bond Formation

Applications of α-Keto Carbocations in Carbon-Carbon and Carbon-Nitrogen Bond Formation

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This thesis describes synthetic applications of α-keto carbocations, which represent potentially useful, but poorly studied, reversed polarity equivalents of enolates. In the first chapter, a Ag(I) – mediated method for the nucleophilic displacement of α-halocarbonyl compounds to construct carbon-ca...

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Bibliographic Details
Main Author: Lai, Ping Shan
Other Authors: Taylor, Mark S.
Language:en_ca
Published: 2011
Subjects:
carbocation
stereoselectivity
0490
Online Access:http://hdl.handle.net/1807/32798

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