Mechanisms of Platinum Group Metal Catalysis Investigated by Experimental and Theoretical Methods
The results of kinetic isotope determination and computational studies on Noyori-type catalytic systems for the hydrogenation of ketones are presented. The catalysts examined include RuH2(NHCMe2CMe2NH2)(R-binap) and RuH(NHCMe2CMe2NH2)(PPh3)2. These complexes are active catalysts for ketone hydroge...
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| Language: | en_ca |
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2009
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| Online Access: | http://hdl.handle.net/1807/29959 |