Ruthenium 4,5-diazafluorene Complexes and their Reactivity
The reaction between RuCl2(PPh3)3 and 4,5-diazafluorene (LH) produced the orange, air sensitive RuCl2(LH)(PPh3)2 (1). Exposing this complex to air led to the oxidation of the CH2 group on the central ring of LH to a carbonyl group. RuCl2(LH)(dppb) (3) was synthesized but did not show the same rea...
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| Language: | en_ca |
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2009
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| Online Access: | http://hdl.handle.net/1807/18891 |