Synthesis and Characterization of New Boron-Nitrogen and Boron-Nitrogen-Phosphorus Systems
The preparative and derivative chemistry of organoborane compounds that contain silicon-nitrogen functional groups is both diverse and synthetically useful. The wide variety of reactions that can occur at boron, in combination with facile cleavage of the Si-N bond, makes them potential precursors to...
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ndltd-TCU-oai-etd.tcu.edu-etd-03162010-1235382013-01-08T02:48:36Z Synthesis and Characterization of New Boron-Nitrogen and Boron-Nitrogen-Phosphorus Systems Cui, Jian College of Science and Engineering The preparative and derivative chemistry of organoborane compounds that contain silicon-nitrogen functional groups is both diverse and synthetically useful. The wide variety of reactions that can occur at boron, in combination with facile cleavage of the Si-N bond, makes them potential precursors to polymeric B-N systems. We report here on the synthesis, characterization, and reactivity of three representative examples of the title systems of general types 1 and 2. Some of these systems are being studied as the precursors to new types of inorganic-organic hybrid polymers and/or novel ring systems. Robert H. Neilson Texas Christian University 2010-03-16 text application/pdf application/msword http://etd.tcu.edu/etdfiles/available/etd-03162010-123538/ http://etd.tcu.edu/etdfiles/available/etd-03162010-123538/ en unrestricted I hereby certify that, if appropriate, I have obtained and attached hereto a written permission statement from the owner(s) of each third party copyrighted matter to be included in my thesis, dissertation, or project report, allowing distribution as specified below. I certify that the version I submitted is the same as that approved by my advisory committee. I hereby grant to TCU or its agents the non-exclusive license to archive and make accessible, under the conditions specified below, my thesis, dissertation, or project report in whole or in part in all forms of media, now or hereafter known. I retain all other ownership rights to the copyright of the thesis, dissertation or project report. I also retain the right to use in future works (such as articles or books) all or part of this thesis, dissertation, or project report. |
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College of Science and Engineering Cui, Jian Synthesis and Characterization of New Boron-Nitrogen and Boron-Nitrogen-Phosphorus Systems |
description |
The preparative and derivative chemistry of organoborane compounds that contain silicon-nitrogen functional groups is both diverse and synthetically useful. The wide variety of reactions that can occur at boron, in combination with facile cleavage of the Si-N bond, makes them potential precursors to polymeric B-N systems.
We report here on the synthesis, characterization, and reactivity of three representative examples of the title systems of general types 1 and 2. Some of these systems are being studied as the precursors to new types of inorganic-organic hybrid polymers and/or novel ring systems. |
author2 |
Robert H. Neilson |
author_facet |
Robert H. Neilson Cui, Jian |
author |
Cui, Jian |
author_sort |
Cui, Jian |
title |
Synthesis and Characterization of New Boron-Nitrogen and Boron-Nitrogen-Phosphorus Systems |
title_short |
Synthesis and Characterization of New Boron-Nitrogen and Boron-Nitrogen-Phosphorus Systems |
title_full |
Synthesis and Characterization of New Boron-Nitrogen and Boron-Nitrogen-Phosphorus Systems |
title_fullStr |
Synthesis and Characterization of New Boron-Nitrogen and Boron-Nitrogen-Phosphorus Systems |
title_full_unstemmed |
Synthesis and Characterization of New Boron-Nitrogen and Boron-Nitrogen-Phosphorus Systems |
title_sort |
synthesis and characterization of new boron-nitrogen and boron-nitrogen-phosphorus systems |
publisher |
Texas Christian University |
publishDate |
2010 |
url |
http://etd.tcu.edu/etdfiles/available/etd-03162010-123538/ |
work_keys_str_mv |
AT cuijian synthesisandcharacterizationofnewboronnitrogenandboronnitrogenphosphorussystems |
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1716502451214876672 |