Decomposition of Novel Diazosugars: Effects on Regioselectivity

Bibliographic Details
Main Author:	Malich, Ashley M.
Language:	English
Published:	Youngstown State University / OhioLINK 2008
Subjects:	Chemistry Organic Chemistry diazosugars decomposition chemistry rhodium catalyst xylose
Online Access:	http://rave.ohiolink.edu/etdc/view?acc_num=ysu1222195006

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spelling	ndltd-OhioLink-oai-etd.ohiolink.edu-ysu12221950062021-08-03T06:17:54Z Decomposition of Novel Diazosugars: Effects on Regioselectivity Malich, Ashley M. Chemistry Organic Chemistry diazosugars decomposition chemistry rhodium catalyst xylose The following work describes the construction and decomposition of azidodeoxy sugars with diazoesters attached. The fate of the projected carbeniod intermediate formed in the presence of a rhodium(II) catalyst resulted in the products of inter- and intramolecular imine formation however, no C-H insertion onto the furanose platform was observed. This research also led to the formation of ketone derivatives and dimeric ethers. 2008-09-24 English text Youngstown State University / OhioLINK http://rave.ohiolink.edu/etdc/view?acc_num=ysu1222195006 http://rave.ohiolink.edu/etdc/view?acc_num=ysu1222195006 unrestricted This thesis or dissertation is protected by copyright: all rights reserved. It may not be copied or redistributed beyond the terms of applicable copyright laws.
collection	NDLTD
language	English
sources	NDLTD
topic	Chemistry Organic Chemistry diazosugars decomposition chemistry rhodium catalyst xylose
spellingShingle	Chemistry Organic Chemistry diazosugars decomposition chemistry rhodium catalyst xylose Malich, Ashley M. Decomposition of Novel Diazosugars: Effects on Regioselectivity
author	Malich, Ashley M.
author_facet	Malich, Ashley M.
author_sort	Malich, Ashley M.
title	Decomposition of Novel Diazosugars: Effects on Regioselectivity
title_short	Decomposition of Novel Diazosugars: Effects on Regioselectivity
title_full	Decomposition of Novel Diazosugars: Effects on Regioselectivity
title_fullStr	Decomposition of Novel Diazosugars: Effects on Regioselectivity
title_full_unstemmed	Decomposition of Novel Diazosugars: Effects on Regioselectivity
title_sort	decomposition of novel diazosugars: effects on regioselectivity
publisher	Youngstown State University / OhioLINK
publishDate	2008
url	http://rave.ohiolink.edu/etdc/view?acc_num=ysu1222195006
work_keys_str_mv	AT malichashleym decompositionofnoveldiazosugarseffectsonregioselectivity
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Decomposition of Novel Diazosugars: Effects on Regioselectivity

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