The Thermal and Mechanical Characteristics of Lithiated PEO LAGP Composite Electrolytes

Bibliographic Details
Main Author: Denney, Jacob Michael
Language:English
Published: Wright State University / OhioLINK 2020
Subjects:
Online Access:http://rave.ohiolink.edu/etdc/view?acc_num=wright1609971094548742
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spelling ndltd-OhioLink-oai-etd.ohiolink.edu-wright16099710945487422021-08-03T07:16:40Z The Thermal and Mechanical Characteristics of Lithiated PEO LAGP Composite Electrolytes Denney, Jacob Michael Materials Science Mechanical Engineering solid-state flexible lithium based batteries polymer-ceramic composites polymer-ceramic composite electrolytes Lithium-ion batteries are part of a multibillion-dollar industry that strives to meet the demands for an increasingly advanced technological future. Flexible batteries can be easily adapted from emerging novel wearable electronics to electrical vehicles and advanced solar panels. Solid-state batteries can greatly reduce the risk of fire or leaking hazardous materials due to puncture. For the development of solid-state flexible lithium based batteries polymer-ceramic composites are attractive electrolyte candidates because of their combined properties, such as electrical, thermal and mechanical properties, that not only overcome limitations from the base materials but may also render some enhanced performances resulting from the interaction among the components. In this study polymer-ceramic composite electrolytes consisting of polyethylene oxide (PEO), Li1.4Al0.4Ge1.6(PO4)3 (LAGP) and two lithium salts (LiTFSI and LiBF4) are studied. Thermogravimetric Analysis (TGA), Differential Scanning Calorimetry (DSC), and Dynamic Mechanical Analysis (DMA) are used to characterize their thermal and mechanical characteristics. The glass transition temperature, onset of melting, the decomposition temperature, the characteristics of the stiffness and strength as a function of temperature are determined and analyzed. It is aimed to determine how the lithium salts and LAGP ceramic impact the thermal and mechanical properties of the electrolytes. 2020 English text Wright State University / OhioLINK http://rave.ohiolink.edu/etdc/view?acc_num=wright1609971094548742 http://rave.ohiolink.edu/etdc/view?acc_num=wright1609971094548742 unrestricted This thesis or dissertation is protected by copyright: some rights reserved. It is licensed for use under a Creative Commons license. Specific terms and permissions are available from this document's record in the OhioLINK ETD Center.
collection NDLTD
language English
sources NDLTD
topic Materials Science
Mechanical Engineering
solid-state flexible lithium based batteries
polymer-ceramic composites
polymer-ceramic composite electrolytes
spellingShingle Materials Science
Mechanical Engineering
solid-state flexible lithium based batteries
polymer-ceramic composites
polymer-ceramic composite electrolytes
Denney, Jacob Michael
The Thermal and Mechanical Characteristics of Lithiated PEO LAGP Composite Electrolytes
author Denney, Jacob Michael
author_facet Denney, Jacob Michael
author_sort Denney, Jacob Michael
title The Thermal and Mechanical Characteristics of Lithiated PEO LAGP Composite Electrolytes
title_short The Thermal and Mechanical Characteristics of Lithiated PEO LAGP Composite Electrolytes
title_full The Thermal and Mechanical Characteristics of Lithiated PEO LAGP Composite Electrolytes
title_fullStr The Thermal and Mechanical Characteristics of Lithiated PEO LAGP Composite Electrolytes
title_full_unstemmed The Thermal and Mechanical Characteristics of Lithiated PEO LAGP Composite Electrolytes
title_sort thermal and mechanical characteristics of lithiated peo lagp composite electrolytes
publisher Wright State University / OhioLINK
publishDate 2020
url http://rave.ohiolink.edu/etdc/view?acc_num=wright1609971094548742
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