Synthesis and Electrodeposition of Mixed Metal Trinuclear Clusters of Molybdenum and Chromium in Ionic Liquid onto a Platinum Electrode

Bibliographic Details
Main Author:	Frock, Lynn Renee
Language:	English
Published:	Wright State University / OhioLINK 2012
Subjects:	Analytical Chemistry Energy Molybdenum electrodeposition
Online Access:	http://rave.ohiolink.edu/etdc/view?acc_num=wright1357925302

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spelling	ndltd-OhioLink-oai-etd.ohiolink.edu-wright13579253022021-08-03T05:20:49Z Synthesis and Electrodeposition of Mixed Metal Trinuclear Clusters of Molybdenum and Chromium in Ionic Liquid onto a Platinum Electrode Frock, Lynn Renee Analytical Chemistry Energy Molybdenum electrodeposition Electrochemical properties of [Mo3O2(O2CCH3)6(H2O)(CF3SO2H)2 and [Cr2Mo(u2-CH3COO)6(u3-O)(H2O)3][CF3SO3] in 1-ethyl-3-methylimidazolium bis(pentafluoroethanesulfonyl)-imide ionic liquid was investigated. Cyclic voltammograms using a Platinum electrode indicated deposition had occurred for the [Mo3O2(O2CCH3)6(H2O)(CF3SO2H)2 metal cluster but had not for the polynuclear complex [Cr2Mo(u2-CH3COO)6(u3-O)(H2O)3][CF3SO3]. Constant potential electrolysis of -1.23 V using a platinum foil electrode was performed. Scanning electron microscopy in combination with energy dispersion spectroscopy confirmed that deposition had occurred. 2012 English text Wright State University / OhioLINK http://rave.ohiolink.edu/etdc/view?acc_num=wright1357925302 http://rave.ohiolink.edu/etdc/view?acc_num=wright1357925302 unrestricted This thesis or dissertation is protected by copyright: all rights reserved. It may not be copied or redistributed beyond the terms of applicable copyright laws.
collection	NDLTD
language	English
sources	NDLTD
topic	Analytical Chemistry Energy Molybdenum electrodeposition
spellingShingle	Analytical Chemistry Energy Molybdenum electrodeposition Frock, Lynn Renee Synthesis and Electrodeposition of Mixed Metal Trinuclear Clusters of Molybdenum and Chromium in Ionic Liquid onto a Platinum Electrode
author	Frock, Lynn Renee
author_facet	Frock, Lynn Renee
author_sort	Frock, Lynn Renee
title	Synthesis and Electrodeposition of Mixed Metal Trinuclear Clusters of Molybdenum and Chromium in Ionic Liquid onto a Platinum Electrode
title_short	Synthesis and Electrodeposition of Mixed Metal Trinuclear Clusters of Molybdenum and Chromium in Ionic Liquid onto a Platinum Electrode
title_full	Synthesis and Electrodeposition of Mixed Metal Trinuclear Clusters of Molybdenum and Chromium in Ionic Liquid onto a Platinum Electrode
title_fullStr	Synthesis and Electrodeposition of Mixed Metal Trinuclear Clusters of Molybdenum and Chromium in Ionic Liquid onto a Platinum Electrode
title_full_unstemmed	Synthesis and Electrodeposition of Mixed Metal Trinuclear Clusters of Molybdenum and Chromium in Ionic Liquid onto a Platinum Electrode
title_sort	synthesis and electrodeposition of mixed metal trinuclear clusters of molybdenum and chromium in ionic liquid onto a platinum electrode
publisher	Wright State University / OhioLINK
publishDate	2012
url	http://rave.ohiolink.edu/etdc/view?acc_num=wright1357925302
work_keys_str_mv	AT frocklynnrenee synthesisandelectrodepositionofmixedmetaltrinuclearclustersofmolybdenumandchromiuminionicliquidontoaplatinumelectrode
_version_	1719418939494105088

Synthesis and Electrodeposition of Mixed Metal Trinuclear Clusters of Molybdenum and Chromium in Ionic Liquid onto a Platinum Electrode

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